Synthesis and characterization of new schiff bases derived from benzaldehyde with o-phenylenediamine and1,3-diaminopropane and their Ni(II), Cu(II), Zn(II) and Co(II) complexes / Mazlin Mohideen

Two new Schiff base ligands are prepared by condensation reaction of benzaldehyde with o-phenylenediamine and 1,3-diaminopropane in the ratio of 2:1. The complexes of two Schiff bases, bis(benzaldehyde)o-phenylenediamine (baOPD) and bis(benzaldehyde)1,3-diaminoprapane (baprop) with Ni(II), Cu(II), Z...

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Main Author:	Mohideen, Mazlin
Format:	Thesis
Language:	English
Published:	2007
Online Access:	https://ir.uitm.edu.my/id/eprint/101133/1/%EF%BB%BF101133.pdf
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id	my-uitm-ir.101133
record_format	uketd_dc
spelling	my-uitm-ir.1011332024-08-27T17:24:46Z Synthesis and characterization of new schiff bases derived from benzaldehyde with o-phenylenediamine and1,3-diaminopropane and their Ni(II), Cu(II), Zn(II) and Co(II) complexes / Mazlin Mohideen 2007 Mohideen, Mazlin Two new Schiff base ligands are prepared by condensation reaction of benzaldehyde with o-phenylenediamine and 1,3-diaminopropane in the ratio of 2:1. The complexes of two Schiff bases, bis(benzaldehyde)o-phenylenediamine (baOPD) and bis(benzaldehyde)1,3-diaminoprapane (baprop) with Ni(II), Cu(II), Zn(II) and Co(II) have been successfully prepared. The metal complexes are prepared by the direct method in the ratio of 1:1 (baOPD/baprop : metal) and the template method in the ratio 2:1:1 (benzaldehyde : OPD/1,3-diaminopropane : metal). Elemental analysis data, and magnetic susceptibility values have been obtained, IR and 1H NMR spectral studies have been carried out to suggest tentative structures for the characterization of the complexes and ligands. The results suggest that the direct method is better than template method for complexation and the Schiff bases are bidentate ligands (NN) coordinating through the azomethine nitrogens. 2007 Thesis https://ir.uitm.edu.my/id/eprint/101133/ https://ir.uitm.edu.my/id/eprint/101133/1/%EF%BB%BF101133.pdf text en public degree Universiti Teknologi MARA (UiTM) Faculty of Applied Sciences
institution	Universiti Teknologi MARA
collection	UiTM Institutional Repository
language	English
description	Two new Schiff base ligands are prepared by condensation reaction of benzaldehyde with o-phenylenediamine and 1,3-diaminopropane in the ratio of 2:1. The complexes of two Schiff bases, bis(benzaldehyde)o-phenylenediamine (baOPD) and bis(benzaldehyde)1,3-diaminoprapane (baprop) with Ni(II), Cu(II), Zn(II) and Co(II) have been successfully prepared. The metal complexes are prepared by the direct method in the ratio of 1:1 (baOPD/baprop : metal) and the template method in the ratio 2:1:1 (benzaldehyde : OPD/1,3-diaminopropane : metal). Elemental analysis data, and magnetic susceptibility values have been obtained, IR and 1H NMR spectral studies have been carried out to suggest tentative structures for the characterization of the complexes and ligands. The results suggest that the direct method is better than template method for complexation and the Schiff bases are bidentate ligands (NN) coordinating through the azomethine nitrogens.
format	Thesis
qualification_level	Bachelor degree
author	Mohideen, Mazlin
spellingShingle	Mohideen, Mazlin Synthesis and characterization of new schiff bases derived from benzaldehyde with o-phenylenediamine and1,3-diaminopropane and their Ni(II), Cu(II), Zn(II) and Co(II) complexes / Mazlin Mohideen
author_facet	Mohideen, Mazlin
author_sort	Mohideen, Mazlin
title	Synthesis and characterization of new schiff bases derived from benzaldehyde with o-phenylenediamine and1,3-diaminopropane and their Ni(II), Cu(II), Zn(II) and Co(II) complexes / Mazlin Mohideen
title_short	Synthesis and characterization of new schiff bases derived from benzaldehyde with o-phenylenediamine and1,3-diaminopropane and their Ni(II), Cu(II), Zn(II) and Co(II) complexes / Mazlin Mohideen
title_full	Synthesis and characterization of new schiff bases derived from benzaldehyde with o-phenylenediamine and1,3-diaminopropane and their Ni(II), Cu(II), Zn(II) and Co(II) complexes / Mazlin Mohideen
title_fullStr	Synthesis and characterization of new schiff bases derived from benzaldehyde with o-phenylenediamine and1,3-diaminopropane and their Ni(II), Cu(II), Zn(II) and Co(II) complexes / Mazlin Mohideen
title_full_unstemmed	Synthesis and characterization of new schiff bases derived from benzaldehyde with o-phenylenediamine and1,3-diaminopropane and their Ni(II), Cu(II), Zn(II) and Co(II) complexes / Mazlin Mohideen
title_sort	synthesis and characterization of new schiff bases derived from benzaldehyde with o-phenylenediamine and1,3-diaminopropane and their ni(ii), cu(ii), zn(ii) and co(ii) complexes / mazlin mohideen
granting_institution	Universiti Teknologi MARA (UiTM)
granting_department	Faculty of Applied Sciences
publishDate	2007
url	https://ir.uitm.edu.my/id/eprint/101133/1/%EF%BB%BF101133.pdf
_version_	1811769133006585856

Synthesis and characterization of new schiff bases derived from benzaldehyde with o-phenylenediamine and1,3-diaminopropane and their Ni(II), Cu(II), Zn(II) and Co(II) complexes / Mazlin Mohideen

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