Schiff bases as corrosion inhibitors for copper in hydrochloric acid / Nurhadilah Che Harun

Five Schiff bases, N,N’-bis(salicylaldehyde)-l,2-ethylenediamine (salen N,N’-bis(3methoxysalicylidene)-l,2-ethylenediamine (MeO-salen), N,N'-bis (5- nitrosalicylidene)-l,2-ethylenediamine (N02-salen),N,N'-bis(2-hydroxy acetophenone) (hapen) and N,N’-bis(2-hydroxy-5-nitroacetophenone) (NO2-...

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Main Author: Che Harun, Nurhadilah
Format: Thesis
Language:English
Published: 2010
Online Access:https://ir.uitm.edu.my/id/eprint/103871/1/103871.pdf
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spelling my-uitm-ir.1038712024-09-28T15:57:29Z Schiff bases as corrosion inhibitors for copper in hydrochloric acid / Nurhadilah Che Harun 2010 Che Harun, Nurhadilah Five Schiff bases, N,N’-bis(salicylaldehyde)-l,2-ethylenediamine (salen N,N’-bis(3methoxysalicylidene)-l,2-ethylenediamine (MeO-salen), N,N'-bis (5- nitrosalicylidene)-l,2-ethylenediamine (N02-salen),N,N'-bis(2-hydroxy acetophenone) (hapen) and N,N’-bis(2-hydroxy-5-nitroacetophenone) (NO2- hapen) have been successfully synthesized by reaction of ethylenediamine with the appropriate aldehye or ketone in the ratio 1:2. The Schiff base ligands are characterized by using elemental analysis, infrared spectroscopy, JH NMR spectroscopy and melting point determination. The compounds are examined for their inhibitive effect toward corrosion of copper metal in 1M hydrochloric acid by using the weight loss method. The effect of different concentrations of each compound, ranging from 0.01M to 0.0001M toward inhibiting corrosion is investigated. The results show the most effective Schiff base as an inhibitor of corrosion is MeO-salen at the concentration 0.01M with inhibiting efficiency of 64.90%. 2010 Thesis https://ir.uitm.edu.my/id/eprint/103871/ https://ir.uitm.edu.my/id/eprint/103871/1/103871.pdf text en public degree Universiti Teknologi MARA (UiTM) Faculty of Applied Sciences Bahron, Hadariah
institution Universiti Teknologi MARA
collection UiTM Institutional Repository
language English
advisor Bahron, Hadariah
description Five Schiff bases, N,N’-bis(salicylaldehyde)-l,2-ethylenediamine (salen N,N’-bis(3methoxysalicylidene)-l,2-ethylenediamine (MeO-salen), N,N'-bis (5- nitrosalicylidene)-l,2-ethylenediamine (N02-salen),N,N'-bis(2-hydroxy acetophenone) (hapen) and N,N’-bis(2-hydroxy-5-nitroacetophenone) (NO2- hapen) have been successfully synthesized by reaction of ethylenediamine with the appropriate aldehye or ketone in the ratio 1:2. The Schiff base ligands are characterized by using elemental analysis, infrared spectroscopy, JH NMR spectroscopy and melting point determination. The compounds are examined for their inhibitive effect toward corrosion of copper metal in 1M hydrochloric acid by using the weight loss method. The effect of different concentrations of each compound, ranging from 0.01M to 0.0001M toward inhibiting corrosion is investigated. The results show the most effective Schiff base as an inhibitor of corrosion is MeO-salen at the concentration 0.01M with inhibiting efficiency of 64.90%.
format Thesis
qualification_level Bachelor degree
author Che Harun, Nurhadilah
spellingShingle Che Harun, Nurhadilah
Schiff bases as corrosion inhibitors for copper in hydrochloric acid / Nurhadilah Che Harun
author_facet Che Harun, Nurhadilah
author_sort Che Harun, Nurhadilah
title Schiff bases as corrosion inhibitors for copper in hydrochloric acid / Nurhadilah Che Harun
title_short Schiff bases as corrosion inhibitors for copper in hydrochloric acid / Nurhadilah Che Harun
title_full Schiff bases as corrosion inhibitors for copper in hydrochloric acid / Nurhadilah Che Harun
title_fullStr Schiff bases as corrosion inhibitors for copper in hydrochloric acid / Nurhadilah Che Harun
title_full_unstemmed Schiff bases as corrosion inhibitors for copper in hydrochloric acid / Nurhadilah Che Harun
title_sort schiff bases as corrosion inhibitors for copper in hydrochloric acid / nurhadilah che harun
granting_institution Universiti Teknologi MARA (UiTM)
granting_department Faculty of Applied Sciences
publishDate 2010
url https://ir.uitm.edu.my/id/eprint/103871/1/103871.pdf
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