Catalytic co-pyrolysis of palm kernel shell and polypropylene using metal incorporated mesoporous zeolite for high-quality bio-oil / Aizatul Hikmah Zulkafli

The increasing global fuel consumption and growing environmental concerns are the impetuses to explore alternative energy that is clean and renewable for fuel production. Converting biomass and plastic waste into high-value fuel and chemicals via catalytic co-pyrolysis and co-pyrolysis technique may...

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Main Author: Zulkafli, Aizatul Hikmah
Format: Thesis
Language:English
Published: 2024
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/106874/1/106874.pdf
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spelling my-uitm-ir.1068742024-11-27T08:11:41Z Catalytic co-pyrolysis of palm kernel shell and polypropylene using metal incorporated mesoporous zeolite for high-quality bio-oil / Aizatul Hikmah Zulkafli 2024 Zulkafli, Aizatul Hikmah Physical and theoretical chemistry Chemical engineering The increasing global fuel consumption and growing environmental concerns are the impetuses to explore alternative energy that is clean and renewable for fuel production. Converting biomass and plastic waste into high-value fuel and chemicals via catalytic co-pyrolysis and co-pyrolysis technique may provide a sustainable remediation to this problem. The highest bio-oil yield of 67.65 wt.% was obtained at 600 °C and PKS:PP ratio of 25:75. Positive synergistic effect on the production of hydrocarbons and esters, as well as the inhibition of acids and ketones were prominent at 500 °C and PKS:PP ratio of 75:25. The plausible reaction mechanism for formation of major products was proposed. Co-pyrolysis of PKS and PP has generated bio-oil with a larger hydrogen and carbon content and lower oxygen composition compared to PKS bio-oil. 2024 Thesis https://ir.uitm.edu.my/id/eprint/106874/ https://ir.uitm.edu.my/id/eprint/106874/1/106874.pdf text en public masters Universiti Teknologi MARA (UiTM) Faculty of Chemical Engineering Hassan, Hamizura
institution Universiti Teknologi MARA
collection UiTM Institutional Repository
language English
advisor Hassan, Hamizura
topic Physical and theoretical chemistry
Chemical engineering
spellingShingle Physical and theoretical chemistry
Chemical engineering
Zulkafli, Aizatul Hikmah
Catalytic co-pyrolysis of palm kernel shell and polypropylene using metal incorporated mesoporous zeolite for high-quality bio-oil / Aizatul Hikmah Zulkafli
description The increasing global fuel consumption and growing environmental concerns are the impetuses to explore alternative energy that is clean and renewable for fuel production. Converting biomass and plastic waste into high-value fuel and chemicals via catalytic co-pyrolysis and co-pyrolysis technique may provide a sustainable remediation to this problem. The highest bio-oil yield of 67.65 wt.% was obtained at 600 °C and PKS:PP ratio of 25:75. Positive synergistic effect on the production of hydrocarbons and esters, as well as the inhibition of acids and ketones were prominent at 500 °C and PKS:PP ratio of 75:25. The plausible reaction mechanism for formation of major products was proposed. Co-pyrolysis of PKS and PP has generated bio-oil with a larger hydrogen and carbon content and lower oxygen composition compared to PKS bio-oil.
format Thesis
qualification_level Master's degree
author Zulkafli, Aizatul Hikmah
author_facet Zulkafli, Aizatul Hikmah
author_sort Zulkafli, Aizatul Hikmah
title Catalytic co-pyrolysis of palm kernel shell and polypropylene using metal incorporated mesoporous zeolite for high-quality bio-oil / Aizatul Hikmah Zulkafli
title_short Catalytic co-pyrolysis of palm kernel shell and polypropylene using metal incorporated mesoporous zeolite for high-quality bio-oil / Aizatul Hikmah Zulkafli
title_full Catalytic co-pyrolysis of palm kernel shell and polypropylene using metal incorporated mesoporous zeolite for high-quality bio-oil / Aizatul Hikmah Zulkafli
title_fullStr Catalytic co-pyrolysis of palm kernel shell and polypropylene using metal incorporated mesoporous zeolite for high-quality bio-oil / Aizatul Hikmah Zulkafli
title_full_unstemmed Catalytic co-pyrolysis of palm kernel shell and polypropylene using metal incorporated mesoporous zeolite for high-quality bio-oil / Aizatul Hikmah Zulkafli
title_sort catalytic co-pyrolysis of palm kernel shell and polypropylene using metal incorporated mesoporous zeolite for high-quality bio-oil / aizatul hikmah zulkafli
granting_institution Universiti Teknologi MARA (UiTM)
granting_department Faculty of Chemical Engineering
publishDate 2024
url https://ir.uitm.edu.my/id/eprint/106874/1/106874.pdf
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