Synthesis of tin octoate coating on ceramic support derived from ceramic waste in production of polylactic acid / Amira Nadzirah Suhaidi

Production of polylactic acid (PLA) using liquid tin octotate (homogeneous catalyst) can lead to degradation of PLA after certain time. The aim of this study is to fabricate heterogeneous tin octoate on ceramic support from ceramic waste in the production of polylactic acid. The research began with...

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Main Author:	Suhaidi, Amira Nadzirah
Format:	Thesis
Language:	English
Published:	2021
Subjects:	Ceramic technology Pottery
Online Access:	https://ir.uitm.edu.my/id/eprint/60094/1/60094.pdf
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id	my-uitm-ir.60094
record_format	uketd_dc
spelling	my-uitm-ir.600942022-05-23T02:09:52Z Synthesis of tin octoate coating on ceramic support derived from ceramic waste in production of polylactic acid / Amira Nadzirah Suhaidi 2021-06 Suhaidi, Amira Nadzirah Ceramic technology. Pottery Production of polylactic acid (PLA) using liquid tin octotate (homogeneous catalyst) can lead to degradation of PLA after certain time. The aim of this study is to fabricate heterogeneous tin octoate on ceramic support from ceramic waste in the production of polylactic acid. The research began with the collection of ceramic waste collected from sanitary ware company and ceramic support were produced. Next, the support then were coated with tin octoate mixture formulation with variation on sintering temperature, binder, solvent and catalyst concentration. The samples of coating on ceramic support were sent for characterization using EDX and adhesion testing of tape test ASTM D3359. With this analysis, the optimum conditions for the surface coating were formulated using tin octoate of 500ppm, polyethylene glycol (PEG) binder and N,N-dimethylformamide (DMF) solvent and sintered at 200 ℃. Subsequently, the ring opening polymerization of lactide were undergone with different phase of catalyst, initiators and temperature of reaction. The samples of polymerization reaction product were sent for characterization using Fourier Transform Infrared (FTIR) in finding the functional group in the product and UV-Vis Spectrophotometer at absorbance of 232 nm in finding the existence and concentration of the product. The reaction with heterogeneous catalyst achieved highest polymerization rate of 92.4 ppm at 130 ℃ of reaction temperature. Excellence result showed using methanol initiator at polymerization rate of 70.8 ppm of product. This study has proven that the heterogeneous tin octoate with reaction temperature of 130 ℃ and using methanol initiator can be used in the production of polylactic acid. 2021-06 Thesis https://ir.uitm.edu.my/id/eprint/60094/ https://ir.uitm.edu.my/id/eprint/60094/1/60094.pdf text en public masters Universiti Teknologi MARA Faculty of Chemical Engineering Ibrahim, Norliza (Dr.)
institution	Universiti Teknologi MARA
collection	UiTM Institutional Repository
language	English
advisor	Ibrahim, Norliza (Dr.)
topic	Ceramic technology Pottery
spellingShingle	Ceramic technology Pottery Suhaidi, Amira Nadzirah Synthesis of tin octoate coating on ceramic support derived from ceramic waste in production of polylactic acid / Amira Nadzirah Suhaidi
description	Production of polylactic acid (PLA) using liquid tin octotate (homogeneous catalyst) can lead to degradation of PLA after certain time. The aim of this study is to fabricate heterogeneous tin octoate on ceramic support from ceramic waste in the production of polylactic acid. The research began with the collection of ceramic waste collected from sanitary ware company and ceramic support were produced. Next, the support then were coated with tin octoate mixture formulation with variation on sintering temperature, binder, solvent and catalyst concentration. The samples of coating on ceramic support were sent for characterization using EDX and adhesion testing of tape test ASTM D3359. With this analysis, the optimum conditions for the surface coating were formulated using tin octoate of 500ppm, polyethylene glycol (PEG) binder and N,N-dimethylformamide (DMF) solvent and sintered at 200 ℃. Subsequently, the ring opening polymerization of lactide were undergone with different phase of catalyst, initiators and temperature of reaction. The samples of polymerization reaction product were sent for characterization using Fourier Transform Infrared (FTIR) in finding the functional group in the product and UV-Vis Spectrophotometer at absorbance of 232 nm in finding the existence and concentration of the product. The reaction with heterogeneous catalyst achieved highest polymerization rate of 92.4 ppm at 130 ℃ of reaction temperature. Excellence result showed using methanol initiator at polymerization rate of 70.8 ppm of product. This study has proven that the heterogeneous tin octoate with reaction temperature of 130 ℃ and using methanol initiator can be used in the production of polylactic acid.
format	Thesis
qualification_level	Master's degree
author	Suhaidi, Amira Nadzirah
author_facet	Suhaidi, Amira Nadzirah
author_sort	Suhaidi, Amira Nadzirah
title	Synthesis of tin octoate coating on ceramic support derived from ceramic waste in production of polylactic acid / Amira Nadzirah Suhaidi
title_short	Synthesis of tin octoate coating on ceramic support derived from ceramic waste in production of polylactic acid / Amira Nadzirah Suhaidi
title_full	Synthesis of tin octoate coating on ceramic support derived from ceramic waste in production of polylactic acid / Amira Nadzirah Suhaidi
title_fullStr	Synthesis of tin octoate coating on ceramic support derived from ceramic waste in production of polylactic acid / Amira Nadzirah Suhaidi
title_full_unstemmed	Synthesis of tin octoate coating on ceramic support derived from ceramic waste in production of polylactic acid / Amira Nadzirah Suhaidi
title_sort	synthesis of tin octoate coating on ceramic support derived from ceramic waste in production of polylactic acid / amira nadzirah suhaidi
granting_institution	Universiti Teknologi MARA
granting_department	Faculty of Chemical Engineering
publishDate	2021
url	https://ir.uitm.edu.my/id/eprint/60094/1/60094.pdf
_version_	1783735084025643008

Synthesis of tin octoate coating on ceramic support derived from ceramic waste in production of polylactic acid / Amira Nadzirah Suhaidi

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