Effects of hydroxyapatite coating with oxide interlayer on bioactivity performances in CoCrMo alloy

Cobalt-chromium-molybdenum (Co-Cr-Mo) alloys have been reported difficult to bond directly on hard tissues owing to encapsulation by fibrous tissues. Several attempts have been made to improve the situation including coating with a bioactive layer which is mainly hydroxyapatite (HA). Various HA coat...

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Main Author:	Mas Ayu, Hassan
Format:	Thesis
Language:	English
Published:	2015
Subjects:	Q Science (General) TJ Mechanical engineering and machinery
Online Access:	http://umpir.ump.edu.my/id/eprint/13064/19/Effects%20of%20hydroxyapatite%20coating%20with%20oxide%20interlayer%20on%20bioactivity%20performances%20in%20CoCrMo%20alloy.pdf
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spelling	my-ump-ir.130642021-11-08T04:31:27Z Effects of hydroxyapatite coating with oxide interlayer on bioactivity performances in CoCrMo alloy 2015-06 Mas Ayu, Hassan Q Science (General) TJ Mechanical engineering and machinery Cobalt-chromium-molybdenum (Co-Cr-Mo) alloys have been reported difficult to bond directly on hard tissues owing to encapsulation by fibrous tissues. Several attempts have been made to improve the situation including coating with a bioactive layer which is mainly hydroxyapatite (HA). Various HA coating methods have been introduced but massive micro crack surface, delamination and low adhesion strength of HA coating are still the major concerns that cause the harmful release of metal ions. In this study, an oxide interlayer on Co-Cr-Mo alloys was developed through thermal oxidation prior to HA coating with the objective to provide better anchorage of HA coatings on the substrate surface, reduce metal ions release and at the same time enhancing the cell attachment. The thermal oxidation process was conducted in a muffle furnace at different temperatures (850°C, 1050°C and 1250°C) for 3 hours to create an oxide interlayer on the substrate surface. It was followed by coating HA on the bare material and on the oxidized substrates using sol gel dip coating technique. Scratch test results showed that the bonding strength of the HA on the oxide interlayer is markedly higher than the HA coated substrates without oxide interlayer. It seems that rough surface of oxide interlayer provides better mechanical interlocking of HA particles to the substrate surface. Inductively coupled plasma-mass spectrometry (ICP-MS) test illustrated that the release of Co and Cr ions from the HA coated oxidized substrates reduced significantly after 28 days immersion as compared to bare material and HA coated substrates without oxide interlayer. This indicates that oxide interlayer is able to act as an additional barrier to suppress the metal ions release. Similarly, the HA coated substrates with oxide interlayer demonstrate strong attachment and proliferation of cells than the HA coated substrates without oxide interlayer. It is concluded that the introduction of an intermediate oxide layer on Co-Cr-Mo substrate prior to HA coating has shown a positive effect in terms of increment of the adhesion strength of HA coating as well as cell bioactivity performance. 2015-06 Thesis http://umpir.ump.edu.my/id/eprint/13064/ http://umpir.ump.edu.my/id/eprint/13064/19/Effects%20of%20hydroxyapatite%20coating%20with%20oxide%20interlayer%20on%20bioactivity%20performances%20in%20CoCrMo%20alloy.pdf pdf en public phd doctoral Universiti Teknologi Malaysia Faculty of Mechanical Engineering
institution	Universiti Malaysia Pahang Al-Sultan Abdullah
collection	UMPSA Institutional Repository
language	English
topic	Q Science (General) TJ Mechanical engineering and machinery
spellingShingle	Q Science (General) TJ Mechanical engineering and machinery Mas Ayu, Hassan Effects of hydroxyapatite coating with oxide interlayer on bioactivity performances in CoCrMo alloy
description	Cobalt-chromium-molybdenum (Co-Cr-Mo) alloys have been reported difficult to bond directly on hard tissues owing to encapsulation by fibrous tissues. Several attempts have been made to improve the situation including coating with a bioactive layer which is mainly hydroxyapatite (HA). Various HA coating methods have been introduced but massive micro crack surface, delamination and low adhesion strength of HA coating are still the major concerns that cause the harmful release of metal ions. In this study, an oxide interlayer on Co-Cr-Mo alloys was developed through thermal oxidation prior to HA coating with the objective to provide better anchorage of HA coatings on the substrate surface, reduce metal ions release and at the same time enhancing the cell attachment. The thermal oxidation process was conducted in a muffle furnace at different temperatures (850°C, 1050°C and 1250°C) for 3 hours to create an oxide interlayer on the substrate surface. It was followed by coating HA on the bare material and on the oxidized substrates using sol gel dip coating technique. Scratch test results showed that the bonding strength of the HA on the oxide interlayer is markedly higher than the HA coated substrates without oxide interlayer. It seems that rough surface of oxide interlayer provides better mechanical interlocking of HA particles to the substrate surface. Inductively coupled plasma-mass spectrometry (ICP-MS) test illustrated that the release of Co and Cr ions from the HA coated oxidized substrates reduced significantly after 28 days immersion as compared to bare material and HA coated substrates without oxide interlayer. This indicates that oxide interlayer is able to act as an additional barrier to suppress the metal ions release. Similarly, the HA coated substrates with oxide interlayer demonstrate strong attachment and proliferation of cells than the HA coated substrates without oxide interlayer. It is concluded that the introduction of an intermediate oxide layer on Co-Cr-Mo substrate prior to HA coating has shown a positive effect in terms of increment of the adhesion strength of HA coating as well as cell bioactivity performance.
format	Thesis
qualification_name	Doctor of Philosophy (PhD.)
qualification_level	Doctorate
author	Mas Ayu, Hassan
author_facet	Mas Ayu, Hassan
author_sort	Mas Ayu, Hassan
title	Effects of hydroxyapatite coating with oxide interlayer on bioactivity performances in CoCrMo alloy
title_short	Effects of hydroxyapatite coating with oxide interlayer on bioactivity performances in CoCrMo alloy
title_full	Effects of hydroxyapatite coating with oxide interlayer on bioactivity performances in CoCrMo alloy
title_fullStr	Effects of hydroxyapatite coating with oxide interlayer on bioactivity performances in CoCrMo alloy
title_full_unstemmed	Effects of hydroxyapatite coating with oxide interlayer on bioactivity performances in CoCrMo alloy
title_sort	effects of hydroxyapatite coating with oxide interlayer on bioactivity performances in cocrmo alloy
granting_institution	Universiti Teknologi Malaysia
granting_department	Faculty of Mechanical Engineering
publishDate	2015
url	http://umpir.ump.edu.my/id/eprint/13064/19/Effects%20of%20hydroxyapatite%20coating%20with%20oxide%20interlayer%20on%20bioactivity%20performances%20in%20CoCrMo%20alloy.pdf
_version_	1783731976379826176

Effects of hydroxyapatite coating with oxide interlayer on bioactivity performances in CoCrMo alloy

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