Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications

This thesis investigates the use of eco-friendly copper (I) iodide or cuprous iodide (Cul), a p-type semiconductor material, with the incorporation of a chelating agent or organic ligand, called tetramethylethylenediamine (TMED@TMEDA) in the preparation for solid-state dye-sensitized solar cells (DS...

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Main Author: Ayib Rosdi, Zainun
Format: Thesis
Language:English
Published: 2012
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/9010/1/wm.Characterization%20of%20tmed-copper%20%28I%29%20iodide%20%28Cul%29%20thin%20film%20and%20performance%20for%20solid%20state%20dye%20sensitized%20solar%20cell%20applications.pdf
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spelling my-ump-ir.90102023-10-23T08:52:51Z Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications 2012-10 Ayib Rosdi, Zainun TA Engineering (General). Civil engineering (General) TK Electrical engineering. Electronics Nuclear engineering This thesis investigates the use of eco-friendly copper (I) iodide or cuprous iodide (Cul), a p-type semiconductor material, with the incorporation of a chelating agent or organic ligand, called tetramethylethylenediamine (TMED@TMEDA) in the preparation for solid-state dye-sensitized solar cells (DSSC). The Cul solution incorporated with the ligand was dispersed in acetonitrile solvent and deposited on glass and indium-doped tin oxide (ITO) substrates. The thin film is characterized to study its suitability for applications in dye sensitized solar cell (DSSC), a low cost solar cell but having high energy conversion efficiency. From the characterization, compared to that of pure Cul film, its optical properties show improved band-gap energy, while its electrical properties show improved conductivity. An efficient solid-state dye-sensitized solar cell (n-Ti0 2 /dyelp-CuI) with improved stability was fabricated. The TMED-capped Cul crystals not only controls pore-filling of the dyed Ti0 2 layer but also improves the electrical contacts between the Ti0 2 particles, which in general improves the efficiency of the DSSCs. Current-voltage characteristics of the cell showed a larger energy conversion, achieving higher energy conversion efficiency and improved stability. 2012-10 Thesis http://umpir.ump.edu.my/id/eprint/9010/ http://umpir.ump.edu.my/id/eprint/9010/1/wm.Characterization%20of%20tmed-copper%20%28I%29%20iodide%20%28Cul%29%20thin%20film%20and%20performance%20for%20solid%20state%20dye%20sensitized%20solar%20cell%20applications.pdf pdf en public phd doctoral Universiti Teknologi Mara Faculty of Electrical Engineering Mohamad Rusop, Mahmood
institution Universiti Malaysia Pahang Al-Sultan Abdullah
collection UMPSA Institutional Repository
language English
advisor Mohamad Rusop, Mahmood
topic TA Engineering (General)
Civil engineering (General)
TA Engineering (General)
Civil engineering (General)
spellingShingle TA Engineering (General)
Civil engineering (General)
TA Engineering (General)
Civil engineering (General)
Ayib Rosdi, Zainun
Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications
description This thesis investigates the use of eco-friendly copper (I) iodide or cuprous iodide (Cul), a p-type semiconductor material, with the incorporation of a chelating agent or organic ligand, called tetramethylethylenediamine (TMED@TMEDA) in the preparation for solid-state dye-sensitized solar cells (DSSC). The Cul solution incorporated with the ligand was dispersed in acetonitrile solvent and deposited on glass and indium-doped tin oxide (ITO) substrates. The thin film is characterized to study its suitability for applications in dye sensitized solar cell (DSSC), a low cost solar cell but having high energy conversion efficiency. From the characterization, compared to that of pure Cul film, its optical properties show improved band-gap energy, while its electrical properties show improved conductivity. An efficient solid-state dye-sensitized solar cell (n-Ti0 2 /dyelp-CuI) with improved stability was fabricated. The TMED-capped Cul crystals not only controls pore-filling of the dyed Ti0 2 layer but also improves the electrical contacts between the Ti0 2 particles, which in general improves the efficiency of the DSSCs. Current-voltage characteristics of the cell showed a larger energy conversion, achieving higher energy conversion efficiency and improved stability.
format Thesis
qualification_name Doctor of Philosophy (PhD.)
qualification_level Doctorate
author Ayib Rosdi, Zainun
author_facet Ayib Rosdi, Zainun
author_sort Ayib Rosdi, Zainun
title Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications
title_short Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications
title_full Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications
title_fullStr Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications
title_full_unstemmed Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications
title_sort characterization of tmed-copper (i) iodide (cul) thin film and performance for solid state dye sensitized solar cell applications
granting_institution Universiti Teknologi Mara
granting_department Faculty of Electrical Engineering
publishDate 2012
url http://umpir.ump.edu.my/id/eprint/9010/1/wm.Characterization%20of%20tmed-copper%20%28I%29%20iodide%20%28Cul%29%20thin%20film%20and%20performance%20for%20solid%20state%20dye%20sensitized%20solar%20cell%20applications.pdf
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