Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications
This thesis investigates the use of eco-friendly copper (I) iodide or cuprous iodide (Cul), a p-type semiconductor material, with the incorporation of a chelating agent or organic ligand, called tetramethylethylenediamine (TMED@TMEDA) in the preparation for solid-state dye-sensitized solar cells (DS...
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2012
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Online Access: | http://umpir.ump.edu.my/id/eprint/9010/1/wm.Characterization%20of%20tmed-copper%20%28I%29%20iodide%20%28Cul%29%20thin%20film%20and%20performance%20for%20solid%20state%20dye%20sensitized%20solar%20cell%20applications.pdf |
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my-ump-ir.90102023-10-23T08:52:51Z Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications 2012-10 Ayib Rosdi, Zainun TA Engineering (General). Civil engineering (General) TK Electrical engineering. Electronics Nuclear engineering This thesis investigates the use of eco-friendly copper (I) iodide or cuprous iodide (Cul), a p-type semiconductor material, with the incorporation of a chelating agent or organic ligand, called tetramethylethylenediamine (TMED@TMEDA) in the preparation for solid-state dye-sensitized solar cells (DSSC). The Cul solution incorporated with the ligand was dispersed in acetonitrile solvent and deposited on glass and indium-doped tin oxide (ITO) substrates. The thin film is characterized to study its suitability for applications in dye sensitized solar cell (DSSC), a low cost solar cell but having high energy conversion efficiency. From the characterization, compared to that of pure Cul film, its optical properties show improved band-gap energy, while its electrical properties show improved conductivity. An efficient solid-state dye-sensitized solar cell (n-Ti0 2 /dyelp-CuI) with improved stability was fabricated. The TMED-capped Cul crystals not only controls pore-filling of the dyed Ti0 2 layer but also improves the electrical contacts between the Ti0 2 particles, which in general improves the efficiency of the DSSCs. Current-voltage characteristics of the cell showed a larger energy conversion, achieving higher energy conversion efficiency and improved stability. 2012-10 Thesis http://umpir.ump.edu.my/id/eprint/9010/ http://umpir.ump.edu.my/id/eprint/9010/1/wm.Characterization%20of%20tmed-copper%20%28I%29%20iodide%20%28Cul%29%20thin%20film%20and%20performance%20for%20solid%20state%20dye%20sensitized%20solar%20cell%20applications.pdf pdf en public phd doctoral Universiti Teknologi Mara Faculty of Electrical Engineering Mohamad Rusop, Mahmood |
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Universiti Malaysia Pahang Al-Sultan Abdullah |
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UMPSA Institutional Repository |
language |
English |
advisor |
Mohamad Rusop, Mahmood |
topic |
TA Engineering (General) Civil engineering (General) TA Engineering (General) Civil engineering (General) |
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TA Engineering (General) Civil engineering (General) TA Engineering (General) Civil engineering (General) Ayib Rosdi, Zainun Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications |
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This thesis investigates the use of eco-friendly copper (I) iodide or cuprous iodide (Cul), a p-type semiconductor material, with the incorporation of a chelating agent or organic ligand, called tetramethylethylenediamine (TMED@TMEDA) in the preparation for solid-state dye-sensitized solar cells (DSSC). The Cul solution incorporated with the ligand was dispersed in acetonitrile solvent and deposited on glass and indium-doped tin oxide (ITO) substrates. The thin film is characterized to study its suitability for applications in dye sensitized solar cell (DSSC), a low cost solar cell but having high energy conversion efficiency. From the characterization, compared to that of pure Cul film, its optical properties show improved band-gap energy, while its electrical properties show improved conductivity. An efficient solid-state dye-sensitized solar cell (n-Ti0 2 /dyelp-CuI) with improved stability was fabricated. The TMED-capped Cul crystals not only controls pore-filling of the dyed Ti0 2 layer but also improves the electrical contacts between the Ti0 2 particles, which in general improves the efficiency of the DSSCs. Current-voltage characteristics of the cell showed a larger energy conversion, achieving higher energy conversion efficiency and improved stability. |
format |
Thesis |
qualification_name |
Doctor of Philosophy (PhD.) |
qualification_level |
Doctorate |
author |
Ayib Rosdi, Zainun |
author_facet |
Ayib Rosdi, Zainun |
author_sort |
Ayib Rosdi, Zainun |
title |
Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications |
title_short |
Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications |
title_full |
Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications |
title_fullStr |
Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications |
title_full_unstemmed |
Characterization of tmed-copper (I) iodide (Cul) thin film and performance for solid state dye sensitized solar cell applications |
title_sort |
characterization of tmed-copper (i) iodide (cul) thin film and performance for solid state dye sensitized solar cell applications |
granting_institution |
Universiti Teknologi Mara |
granting_department |
Faculty of Electrical Engineering |
publishDate |
2012 |
url |
http://umpir.ump.edu.my/id/eprint/9010/1/wm.Characterization%20of%20tmed-copper%20%28I%29%20iodide%20%28Cul%29%20thin%20film%20and%20performance%20for%20solid%20state%20dye%20sensitized%20solar%20cell%20applications.pdf |
_version_ |
1783731946303520768 |