Structural-functionality changes of corn starches induced by gamma irradiation

The effects of gamma irradiation on the physicochemical and morphological properties of starch samples were investigated. Corn starches with different amylose content (waxy, normal, Hylon V, and Hylon VII) were treated with five doses of gamma irradiation (1 kGy, 5 kGy, 10 kGy, 25 kGy, and 50 kGy)....

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Bibliographic Details
Main Author: Chung, Kok Heung
Format: Thesis
Language:English
English
Published: 2015
Subjects:
Online Access:https://eprints.ums.edu.my/id/eprint/40598/1/24%20PAGES.pdf
https://eprints.ums.edu.my/id/eprint/40598/2/FULLTEXT.pdf
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Summary:The effects of gamma irradiation on the physicochemical and morphological properties of starch samples were investigated. Corn starches with different amylose content (waxy, normal, Hylon V, and Hylon VII) were treated with five doses of gamma irradiation (1 kGy, 5 kGy, 10 kGy, 25 kGy, and 50 kGy). Waxy samples showed an increase of amylose-like fractions when irradiated at 10 kGy. The reduction in apparent amylose content increased with amylose content when underwent irradiation at 25 and 50 kGy. The more drastic decrease in pH value and increase in carboxyl content were observed on Hylon V and VII samples indicated that starches with higher amylose content marked greater susceptibility towards oxidation effect of increasing radiation intensity. Low amylose starches lost their pasting ability when irradiated at 25 kGy and 50 kGy. Results from thermal behavior and pasting profile suggested that lower level of cross-linking effect occurred in Hylon VII samples irradiated at 5 kGy. Severe reduction in pasting properties, gelatinization temperatures and relative crystallinity with increasing irradiation intensity revealed that waxy samples were affected more by gamma irradiation; this also indicated amylopectin was the starch fraction most affected by gamma irradiation. Alteration level was portrayed differently when different kind of physicochemical properties were investigated, in which the pasting properties and crystallinity of starches were more immensely influenced by gamma irradiation while thermal behavior was less affected. Despite the irradiation level, the morphology and crystal pattern of starch granules were found remain unchanged by irradiation.