Evaluation of gypsum based material as coating agent to improve the efficiency of granular urea fertiliser

This study was motivated by the fact that even though urea is the most efficient nitrogen carrier in solid form, it is not efficient in delivering the nutrient to the plant. Approximately 70% of the applied urea fertiliser may be lost to the environment. These losses are due to leaching, decompositi...

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Main Author:	Mohd Ibrahim, Khairul Ridzwan
Format:	Thesis
Language:	English
Published:	2015
Subjects:	Nitrogen fertilizers Gypsum
Online Access:	http://psasir.upm.edu.my/id/eprint/67830/1/FK%202015%20123%20IR.pdf
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id	my-upm-ir.67830
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spelling	my-upm-ir.678302019-04-01T02:23:59Z Evaluation of gypsum based material as coating agent to improve the efficiency of granular urea fertiliser 2015-02 Mohd Ibrahim, Khairul Ridzwan This study was motivated by the fact that even though urea is the most efficient nitrogen carrier in solid form, it is not efficient in delivering the nutrient to the plant. Approximately 70% of the applied urea fertiliser may be lost to the environment. These losses are due to leaching, decomposition and ammonium volatilization in soil, water and air. The common solutions that are available now which is by coating the urea with polymer or sulphur is not being used by farmers in Malaysia primarily due to the high cost. The effect of these coating materials to the environment after prolonged usage is also now being questioned. The study seeks to explore common readily available materials as an alternative coating material. These materials were Portland cement, gypsum plaster, sulphur and zeolite. The materials were also selected based on their availability, processability and price. All these materials also doubles as either nutrients or conditioner to plant and soil. The materials were varied and blended to produce several coating formulations. A coating drum was used to coat the urea with the formulated materials in a dry blend process. The coated urea samples produced were tested for its particles size distribution, crushing strength and dissolution properties. Its dissolution properties were used to benchmark the effectiveness of the coating. Scanning electron microscope was used to further investigate at a microscopic level the coating thickness and the surface morphology of the samples. Cavities were identified in the coating layer of samples and not seen on SCU which may be the cause for a faster diffusion of the samples compared to SCU. Gypsum plaster and sulphur based coating material were found to have performed better than the other formulations which was 13.8% higher than uncoated urea based on the dissolution analysis performed. This formula was further improved where paraffin wax was experimented as a sealant and showed an improvement in dissolution concentration at 24.2% improved efficiency compared to uncoated urea. The final product achieved the highest efficiency at 26%, a marked improvement in dissolution properties than an uncoated urea. This was produced by pretreating (sieving) the base materials (gypsum plaster and sulphur). It is hope that this product will be commercialized and made available to the farmers as an affordable alternative and solution in the near future. The environment will also be benefitting from a more efficient use of nitrogen fertiliser. Nitrogen fertilizers Gypsum 2015-02 Thesis http://psasir.upm.edu.my/id/eprint/67830/ http://psasir.upm.edu.my/id/eprint/67830/1/FK%202015%20123%20IR.pdf text en public masters Universiti Putra Malaysia Nitrogen fertilizers Gypsum
institution	Universiti Putra Malaysia
collection	PSAS Institutional Repository
language	English
topic	Nitrogen fertilizers Gypsum
spellingShingle	Nitrogen fertilizers Gypsum Mohd Ibrahim, Khairul Ridzwan Evaluation of gypsum based material as coating agent to improve the efficiency of granular urea fertiliser
description	This study was motivated by the fact that even though urea is the most efficient nitrogen carrier in solid form, it is not efficient in delivering the nutrient to the plant. Approximately 70% of the applied urea fertiliser may be lost to the environment. These losses are due to leaching, decomposition and ammonium volatilization in soil, water and air. The common solutions that are available now which is by coating the urea with polymer or sulphur is not being used by farmers in Malaysia primarily due to the high cost. The effect of these coating materials to the environment after prolonged usage is also now being questioned. The study seeks to explore common readily available materials as an alternative coating material. These materials were Portland cement, gypsum plaster, sulphur and zeolite. The materials were also selected based on their availability, processability and price. All these materials also doubles as either nutrients or conditioner to plant and soil. The materials were varied and blended to produce several coating formulations. A coating drum was used to coat the urea with the formulated materials in a dry blend process. The coated urea samples produced were tested for its particles size distribution, crushing strength and dissolution properties. Its dissolution properties were used to benchmark the effectiveness of the coating. Scanning electron microscope was used to further investigate at a microscopic level the coating thickness and the surface morphology of the samples. Cavities were identified in the coating layer of samples and not seen on SCU which may be the cause for a faster diffusion of the samples compared to SCU. Gypsum plaster and sulphur based coating material were found to have performed better than the other formulations which was 13.8% higher than uncoated urea based on the dissolution analysis performed. This formula was further improved where paraffin wax was experimented as a sealant and showed an improvement in dissolution concentration at 24.2% improved efficiency compared to uncoated urea. The final product achieved the highest efficiency at 26%, a marked improvement in dissolution properties than an uncoated urea. This was produced by pretreating (sieving) the base materials (gypsum plaster and sulphur). It is hope that this product will be commercialized and made available to the farmers as an affordable alternative and solution in the near future. The environment will also be benefitting from a more efficient use of nitrogen fertiliser.
format	Thesis
qualification_level	Master's degree
author	Mohd Ibrahim, Khairul Ridzwan
author_facet	Mohd Ibrahim, Khairul Ridzwan
author_sort	Mohd Ibrahim, Khairul Ridzwan
title	Evaluation of gypsum based material as coating agent to improve the efficiency of granular urea fertiliser
title_short	Evaluation of gypsum based material as coating agent to improve the efficiency of granular urea fertiliser
title_full	Evaluation of gypsum based material as coating agent to improve the efficiency of granular urea fertiliser
title_fullStr	Evaluation of gypsum based material as coating agent to improve the efficiency of granular urea fertiliser
title_full_unstemmed	Evaluation of gypsum based material as coating agent to improve the efficiency of granular urea fertiliser
title_sort	evaluation of gypsum based material as coating agent to improve the efficiency of granular urea fertiliser
granting_institution	Universiti Putra Malaysia
publishDate	2015
url	http://psasir.upm.edu.my/id/eprint/67830/1/FK%202015%20123%20IR.pdf
_version_	1747812522065395712

Evaluation of gypsum based material as coating agent to improve the efficiency of granular urea fertiliser

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