Adsorption of copper (ii) ions in aqueous samples using effervescence-amino-zeolite

Heavy metals, the non-degradable elements of the earth's crust, have many adverse effects on the human body. Their presence in the water environment poses serious health risks to other living organisms as well. Industrial wastewater also contains large amounts of copper ions, which migrate t...

Full description

Saved in:

Bibliographic Details
Main Author:	Abraheem, Jamjoun Hayfa Alajilani
Format:	Thesis
Language:	English
Published:	2020
Subjects:	Zeolites - Absorption and adsorption Copper - Absorption and adsorption
Online Access:	http://psasir.upm.edu.my/id/eprint/92792/1/FS%202021%2013%20-%20IR.pdf
Tags:	Add Tag No Tags, Be the first to tag this record!

id	my-upm-ir.92792
record_format	uketd_dc
spelling	my-upm-ir.927922022-05-09T09:25:23Z Adsorption of copper (ii) ions in aqueous samples using effervescence-amino-zeolite 2020-11 Abraheem, Jamjoun Hayfa Alajilani Heavy metals, the non-degradable elements of the earth's crust, have many adverse effects on the human body. Their presence in the water environment poses serious health risks to other living organisms as well. Industrial wastewater also contains large amounts of copper ions, which migrate through soil and aquatic streams into the atmosphere and ultimately accumulate along the food chain, causing human beings to face health risks. Excessive human intake of copper ions contributes to severe mucosal irritation and corrosion, hepatic and renal damage, widespread capillary damage, severe gastrointestinal irritation, central nervous system irritation, and potential liver and kidney necrotic changes. Therefore, Cu2+ions are considered for removal. Several products have been used to control sorption contaminants, including granulated activated carbon, zeolite, montmorillonite, peat, and compost. The main objective of the current study was to synthesize and characterize EFF-APTES-zeolite using different techniques. The removal of Cu2+ ions was investigated using synthetic solutions at different ion concentrations, contact time, EFF-APTES-zeolite dosage, temperature, and sample pH. The findings of the current study have shown that EFFAPTES- zeolite has been successfully synthesized and characterized by FT-IR, FESEM and BET methods. The results of the current study also showed that the optimal dose for Cu2+ removal was 20 mg with 99.21%, while the optimum concentration was 100 ppm with 99.20%. Similarly, the pH of 4 is the optimum value for EFF-APTESzeolite to extract 99.99% of Cu2+ metal ions from aqueous water. In the meantime, the contact time of 15 min was the optimum period for the successful removal of Cu2+ from aqueous samples. Lastly, 30℃ was noted to be the best temperature for EFFAPTES- zeolite to efficiently remove Cu2+ ions (99.69%) from aqueous water. The adsorption kinetics analysis demonstrated a pseudo-first-order and pseudo-secondorder adsorption model for Cu2+ ions using EFF-APTES-zeolite. This suggests that the adsorption can be regulated by chemical adsorption. Both the Langmuir and Freundlich models match the balance data well, suggesting the presence of a monolayer adsorption with a high adsorption potential for Cu2+ at different concentrations. Zeolites - Absorption and adsorption Copper - Absorption and adsorption 2020-11 Thesis http://psasir.upm.edu.my/id/eprint/92792/ http://psasir.upm.edu.my/id/eprint/92792/1/FS%202021%2013%20-%20IR.pdf text en public masters Universiti Putra Malaysia Zeolites - Absorption and adsorption Copper - Absorption and adsorption Kamaruzaman, Sazlinda
institution	Universiti Putra Malaysia
collection	PSAS Institutional Repository
language	English
advisor	Kamaruzaman, Sazlinda
topic	Zeolites - Absorption and adsorption Copper - Absorption and adsorption
spellingShingle	Zeolites - Absorption and adsorption Copper - Absorption and adsorption Abraheem, Jamjoun Hayfa Alajilani Adsorption of copper (ii) ions in aqueous samples using effervescence-amino-zeolite
description	Heavy metals, the non-degradable elements of the earth's crust, have many adverse effects on the human body. Their presence in the water environment poses serious health risks to other living organisms as well. Industrial wastewater also contains large amounts of copper ions, which migrate through soil and aquatic streams into the atmosphere and ultimately accumulate along the food chain, causing human beings to face health risks. Excessive human intake of copper ions contributes to severe mucosal irritation and corrosion, hepatic and renal damage, widespread capillary damage, severe gastrointestinal irritation, central nervous system irritation, and potential liver and kidney necrotic changes. Therefore, Cu2+ions are considered for removal. Several products have been used to control sorption contaminants, including granulated activated carbon, zeolite, montmorillonite, peat, and compost. The main objective of the current study was to synthesize and characterize EFF-APTES-zeolite using different techniques. The removal of Cu2+ ions was investigated using synthetic solutions at different ion concentrations, contact time, EFF-APTES-zeolite dosage, temperature, and sample pH. The findings of the current study have shown that EFFAPTES- zeolite has been successfully synthesized and characterized by FT-IR, FESEM and BET methods. The results of the current study also showed that the optimal dose for Cu2+ removal was 20 mg with 99.21%, while the optimum concentration was 100 ppm with 99.20%. Similarly, the pH of 4 is the optimum value for EFF-APTESzeolite to extract 99.99% of Cu2+ metal ions from aqueous water. In the meantime, the contact time of 15 min was the optimum period for the successful removal of Cu2+ from aqueous samples. Lastly, 30℃ was noted to be the best temperature for EFFAPTES- zeolite to efficiently remove Cu2+ ions (99.69%) from aqueous water. The adsorption kinetics analysis demonstrated a pseudo-first-order and pseudo-secondorder adsorption model for Cu2+ ions using EFF-APTES-zeolite. This suggests that the adsorption can be regulated by chemical adsorption. Both the Langmuir and Freundlich models match the balance data well, suggesting the presence of a monolayer adsorption with a high adsorption potential for Cu2+ at different concentrations.
format	Thesis
qualification_level	Master's degree
author	Abraheem, Jamjoun Hayfa Alajilani
author_facet	Abraheem, Jamjoun Hayfa Alajilani
author_sort	Abraheem, Jamjoun Hayfa Alajilani
title	Adsorption of copper (ii) ions in aqueous samples using effervescence-amino-zeolite
title_short	Adsorption of copper (ii) ions in aqueous samples using effervescence-amino-zeolite
title_full	Adsorption of copper (ii) ions in aqueous samples using effervescence-amino-zeolite
title_fullStr	Adsorption of copper (ii) ions in aqueous samples using effervescence-amino-zeolite
title_full_unstemmed	Adsorption of copper (ii) ions in aqueous samples using effervescence-amino-zeolite
title_sort	adsorption of copper (ii) ions in aqueous samples using effervescence-amino-zeolite
granting_institution	Universiti Putra Malaysia
publishDate	2020
url	http://psasir.upm.edu.my/id/eprint/92792/1/FS%202021%2013%20-%20IR.pdf
_version_	1747813768033730560

Adsorption of copper (ii) ions in aqueous samples using effervescence-amino-zeolite

Similar Items