Curing Characteristics And Properties Of Epoxidized Natural Rubber ( ENR )

The cure characteristics of accelerated sulphur vulcanization of epoxidized natural rubber containing 25 mol % of epoxidation ( ENR 25 ) was studied while one grade of unmodified natural rubber - standard Malaysian rubber light ( SMR L ) was used as a control. The influences of different accelera...

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Main Author: Amin, Md. Sadequl
Format: Thesis
Language:English
Published: 1997
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Online Access:http://eprints.usm.my/30695/1/MD._SADEQUL_AMIN.pdf
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spelling my-usm-ep.306952017-04-10T02:12:47Z Curing Characteristics And Properties Of Epoxidized Natural Rubber ( ENR ) 1997-07 Amin, Md. Sadequl QH1 Natural history (General - Including nature conservation, geographical distribution) The cure characteristics of accelerated sulphur vulcanization of epoxidized natural rubber containing 25 mol % of epoxidation ( ENR 25 ) was studied while one grade of unmodified natural rubber - standard Malaysian rubber light ( SMR L ) was used as a control. The influences of different accelerator types - zinc dimethyldithiocarbamate ( ZDMC ), tetramethylthiuram disulphide (TMTD), diphenylguanidine ( DPG ), N-t-butylbenzothiazole-2-sulphenamide (TBBS ), and 2-mercaptobenzothiazole ( MBT ) at various temperatures were investigated. Three vUlcanization systems - conventional high-sulphur vulcanization ( CV ), semi-efficient vulcanization ( semi-EV ) and efficient vUlcanization ( EV ) were also investigated. Mooney Shearing Disk Viscometer ( MV 2000 ) and Moving Die Rheometer ( MDR 2000 ) were used to determine the Mooney scorch time and cure time respectively in the temperature range of 100 to 180 DC. Sifat-sifat pematangan· bagi pemvulkanan getah asli terpoksida yang mengandungi 25 % mol pengepoksidaan ( ENR 25 ) terpecut sulfur telah dikaji sementara getah asli ( SMR L ) telah digunakan sebagai kawalan. Kesan berbagai pemecut - zink dimetilditiokarbamat ( ZDMC ), tetrametiltiuram disulfida (TMTD ), difenilguanidin DPG), N-tbutilbenzotiazol- 2-sulfenamida ( TBBS ) dan 2-merkaptobenzotiazol ( MBT ) pada suhu yang berlainan dikaji. Tiga jenis sistem pemvulkanan - pemvulkanan konvensional bersulfur tinggi (CV ), pemvulkanan semi-efektif ( semi-EV) dan pemvulkanan efektif ( EV ) juga telah dikaji. Mooney Shearing Disk Rheometer ( MV 2000 ) dan Moving Die Rheometer ( MDR 2000 ) masing-masing telah digunakan untuk menentukan masa skorj Mooney dan masa pematangan di dalam julat suhu 1 aaoc hingga 180c. 1997-07 Thesis http://eprints.usm.my/30695/ http://eprints.usm.my/30695/1/MD._SADEQUL_AMIN.pdf application/pdf en public masters Universiti Sains Malaysia Pusat Pengajian Sains Kajihayat
institution Universiti Sains Malaysia
collection USM Institutional Repository
language English
topic QH1 Natural history (General - Including nature conservation
geographical distribution)
spellingShingle QH1 Natural history (General - Including nature conservation
geographical distribution)
Amin, Md. Sadequl
Curing Characteristics And Properties Of Epoxidized Natural Rubber ( ENR )
description The cure characteristics of accelerated sulphur vulcanization of epoxidized natural rubber containing 25 mol % of epoxidation ( ENR 25 ) was studied while one grade of unmodified natural rubber - standard Malaysian rubber light ( SMR L ) was used as a control. The influences of different accelerator types - zinc dimethyldithiocarbamate ( ZDMC ), tetramethylthiuram disulphide (TMTD), diphenylguanidine ( DPG ), N-t-butylbenzothiazole-2-sulphenamide (TBBS ), and 2-mercaptobenzothiazole ( MBT ) at various temperatures were investigated. Three vUlcanization systems - conventional high-sulphur vulcanization ( CV ), semi-efficient vulcanization ( semi-EV ) and efficient vUlcanization ( EV ) were also investigated. Mooney Shearing Disk Viscometer ( MV 2000 ) and Moving Die Rheometer ( MDR 2000 ) were used to determine the Mooney scorch time and cure time respectively in the temperature range of 100 to 180 DC. Sifat-sifat pematangan· bagi pemvulkanan getah asli terpoksida yang mengandungi 25 % mol pengepoksidaan ( ENR 25 ) terpecut sulfur telah dikaji sementara getah asli ( SMR L ) telah digunakan sebagai kawalan. Kesan berbagai pemecut - zink dimetilditiokarbamat ( ZDMC ), tetrametiltiuram disulfida (TMTD ), difenilguanidin DPG), N-tbutilbenzotiazol- 2-sulfenamida ( TBBS ) dan 2-merkaptobenzotiazol ( MBT ) pada suhu yang berlainan dikaji. Tiga jenis sistem pemvulkanan - pemvulkanan konvensional bersulfur tinggi (CV ), pemvulkanan semi-efektif ( semi-EV) dan pemvulkanan efektif ( EV ) juga telah dikaji. Mooney Shearing Disk Rheometer ( MV 2000 ) dan Moving Die Rheometer ( MDR 2000 ) masing-masing telah digunakan untuk menentukan masa skorj Mooney dan masa pematangan di dalam julat suhu 1 aaoc hingga 180c.
format Thesis
qualification_level Master's degree
author Amin, Md. Sadequl
author_facet Amin, Md. Sadequl
author_sort Amin, Md. Sadequl
title Curing Characteristics And Properties Of Epoxidized Natural Rubber ( ENR )
title_short Curing Characteristics And Properties Of Epoxidized Natural Rubber ( ENR )
title_full Curing Characteristics And Properties Of Epoxidized Natural Rubber ( ENR )
title_fullStr Curing Characteristics And Properties Of Epoxidized Natural Rubber ( ENR )
title_full_unstemmed Curing Characteristics And Properties Of Epoxidized Natural Rubber ( ENR )
title_sort curing characteristics and properties of epoxidized natural rubber ( enr )
granting_institution Universiti Sains Malaysia
granting_department Pusat Pengajian Sains Kajihayat
publishDate 1997
url http://eprints.usm.my/30695/1/MD._SADEQUL_AMIN.pdf
_version_ 1747820378967769088