Development Of Various Modified Maize Cob As Adsorbents For Methylene Blue Dye Wastewater Treatment

The adsorption of basic dye, Methylene Blue (MB) onto raw maize cob (RMC), acid modified maize cob (AMMC), ferric oxide (Fe3O4), raw maize cob impregnated with ferric oxide (RMC-Fe3O4) and acid modified maize cob impregnated with ferric oxide (AMMC-Fe3O4) have been investigated in this study. The ef...

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Main Author: Tan, Kah Aik
Format: Thesis
Language:English
Published: 2013
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Online Access:http://eprints.usm.my/45261/1/Tan%20Kah%20Aik24.pdf
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spelling my-usm-ep.452612019-08-22T08:32:49Z Development Of Various Modified Maize Cob As Adsorbents For Methylene Blue Dye Wastewater Treatment 2013-07 Tan, Kah Aik T11.95-12.5 Industrial directories The adsorption of basic dye, Methylene Blue (MB) onto raw maize cob (RMC), acid modified maize cob (AMMC), ferric oxide (Fe3O4), raw maize cob impregnated with ferric oxide (RMC-Fe3O4) and acid modified maize cob impregnated with ferric oxide (AMMC-Fe3O4) have been investigated in this study. The effects of pH, adsorbent dosage, initial dye concentration, contact time and temperature on dye concentration removal and COD reduction were investigated by screening process and optimized by response surface methodology (RSM). All the effects showed statistical significance and the adsorption process using AMMC-Fe3O4 showed the highest effectiveness among the five adsorbents. The adsorption process using AMMC-Fe3O4 obtained the highest percentage of dye concentration removal (99.63%) and COD reduction (99.48%) at the optimum conditions with 0.75 g/100 mL of adsorbent dosage, pH 10.31, 156 mg/L of initial dye concentration for 36 minutes under 38.40 oC. The kinetic experimental data were analyzed using four kinetic equations which include pseudo-first-order model, pseudo-second-order model, external diffusion model and intraparticle diffusion model to determine the mechanism of adsorption and potential rate-controlling step. All five adsorbents showed the best fit with pseudo-second-order kinetic model. The experimental equilibrium data were tested on three isotherm models which included Langmuir isotherm, Fruendlich isotherm, and Temkin isotherm. 2013-07 Thesis http://eprints.usm.my/45261/ http://eprints.usm.my/45261/1/Tan%20Kah%20Aik24.pdf application/pdf en public masters Universiti Sains Malaysia Pusat Pengajian Teknologi Industri
institution Universiti Sains Malaysia
collection USM Institutional Repository
language English
topic T11.95-12.5 Industrial directories
spellingShingle T11.95-12.5 Industrial directories
Tan, Kah Aik
Development Of Various Modified Maize Cob As Adsorbents For Methylene Blue Dye Wastewater Treatment
description The adsorption of basic dye, Methylene Blue (MB) onto raw maize cob (RMC), acid modified maize cob (AMMC), ferric oxide (Fe3O4), raw maize cob impregnated with ferric oxide (RMC-Fe3O4) and acid modified maize cob impregnated with ferric oxide (AMMC-Fe3O4) have been investigated in this study. The effects of pH, adsorbent dosage, initial dye concentration, contact time and temperature on dye concentration removal and COD reduction were investigated by screening process and optimized by response surface methodology (RSM). All the effects showed statistical significance and the adsorption process using AMMC-Fe3O4 showed the highest effectiveness among the five adsorbents. The adsorption process using AMMC-Fe3O4 obtained the highest percentage of dye concentration removal (99.63%) and COD reduction (99.48%) at the optimum conditions with 0.75 g/100 mL of adsorbent dosage, pH 10.31, 156 mg/L of initial dye concentration for 36 minutes under 38.40 oC. The kinetic experimental data were analyzed using four kinetic equations which include pseudo-first-order model, pseudo-second-order model, external diffusion model and intraparticle diffusion model to determine the mechanism of adsorption and potential rate-controlling step. All five adsorbents showed the best fit with pseudo-second-order kinetic model. The experimental equilibrium data were tested on three isotherm models which included Langmuir isotherm, Fruendlich isotherm, and Temkin isotherm.
format Thesis
qualification_level Master's degree
author Tan, Kah Aik
author_facet Tan, Kah Aik
author_sort Tan, Kah Aik
title Development Of Various Modified Maize Cob As Adsorbents For Methylene Blue Dye Wastewater Treatment
title_short Development Of Various Modified Maize Cob As Adsorbents For Methylene Blue Dye Wastewater Treatment
title_full Development Of Various Modified Maize Cob As Adsorbents For Methylene Blue Dye Wastewater Treatment
title_fullStr Development Of Various Modified Maize Cob As Adsorbents For Methylene Blue Dye Wastewater Treatment
title_full_unstemmed Development Of Various Modified Maize Cob As Adsorbents For Methylene Blue Dye Wastewater Treatment
title_sort development of various modified maize cob as adsorbents for methylene blue dye wastewater treatment
granting_institution Universiti Sains Malaysia
granting_department Pusat Pengajian Teknologi Industri
publishDate 2013
url http://eprints.usm.my/45261/1/Tan%20Kah%20Aik24.pdf
_version_ 1747821479346569216