Dilute Sulfuric Acid Hydrolysis Of Red Macroalga Eucheuma Denticulatum With Microwaveassisted Heating For Biochar And Bioethanol Production

Eucheuma denticulatum is a type of red macroalgae which are considered as potential feedstock for biofuel production due to high carbohydrate content, ease of availability and low arable land usage. Being such abundant in carbohydrates, macroalgae can be hydrolysed into fermentable sugars and con...

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Main Author:	Teh, Yong Yi
Format:	Thesis
Language:	English
Published:	2018
Subjects:	T Technology TP Chemical Technology
Online Access:	http://eprints.usm.my/50527/1/Dilute%20Sulfuric%20Acid%20Hydrolysis%20Of%20Red%20Macroalga%20Eucheuma%20Denticulatum%20With%20Microwaveassisted%20Heating%20For%20Biochar%20And%20Bioethanol%20Production.pdf
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spelling	my-usm-ep.505272021-11-17T03:42:13Z Dilute Sulfuric Acid Hydrolysis Of Red Macroalga Eucheuma Denticulatum With Microwaveassisted Heating For Biochar And Bioethanol Production 2018-08-01 Teh, Yong Yi T Technology TP Chemical Technology Eucheuma denticulatum is a type of red macroalgae which are considered as potential feedstock for biofuel production due to high carbohydrate content, ease of availability and low arable land usage. Being such abundant in carbohydrates, macroalgae can be hydrolysed into fermentable sugars and converted to bioethanol by natural microorganims. However, the conventional thermal heating that delivers heat from the surface to center of a material is comparatively slow and inefficient. As a result, the longer heating time gives rise to a dramatic reduction of reducing sugars but higher content of by-products, consequently inhibiting the subsequent fermentation. In this study, acid hydrolysis with microwave-assisted heating of macroalga was conducted in a 2.45 GHz microwave oven with 800W of power. The rapid and efficient of dielectric heating effect of microwave-assisted heating could address aforementioned problem, enhance the hydrolysis process and co-produce biochar, reducing sugars and valuable chemicals. This study was set out to study the properties of biochar as a source of biofuel after macroalga was subjected to microwave-assisted hydrolysis. The hydrolysis reactions were operated at sulfuric acid concentrations of 0.1M and 0.2M, reaction temperatures of 150–170 °C and a heating time of 10 min. The produced biochars were characterized and it was found that biochar qualities were improved with increased elemental carbon content and lower ash and moisture contents. The calorific value of the biochar was intensified up to 45%, and 39% of energy yield was recovered. Apart from biochar, the concentrations of reducing sugars and by-product of hydrolysate were also determined and subsequently converted to bioethanol. The highest total reducing sugars were 51.47 g/L (74.84% yield) along with a low by-product 5-HMF of 0.20 g/L, when the biomass was treated under the conditions at 160 °C with 0.1M H2SO4. The ethanol yield obtained was 0.33 g/g, which corresponded to a 64.21% of yield. As a conclusion, acid hydrolysis with microwave-assisted acid hydrolysis has its great potential applications for the production of bioenergy, nutrient-rich biochar for soil amelioration and value-added chemicals. 2018-08 Thesis http://eprints.usm.my/50527/ http://eprints.usm.my/50527/1/Dilute%20Sulfuric%20Acid%20Hydrolysis%20Of%20Red%20Macroalga%20Eucheuma%20Denticulatum%20With%20Microwaveassisted%20Heating%20For%20Biochar%20And%20Bioethanol%20Production.pdf application/pdf en public phd doctoral Universiti Sains Malaysia Pusat Pengajian Kejuruteraan Kimia
institution	Universiti Sains Malaysia
collection	USM Institutional Repository
language	English
topic	T Technology TP Chemical Technology
spellingShingle	T Technology TP Chemical Technology Teh, Yong Yi Dilute Sulfuric Acid Hydrolysis Of Red Macroalga Eucheuma Denticulatum With Microwaveassisted Heating For Biochar And Bioethanol Production
description	Eucheuma denticulatum is a type of red macroalgae which are considered as potential feedstock for biofuel production due to high carbohydrate content, ease of availability and low arable land usage. Being such abundant in carbohydrates, macroalgae can be hydrolysed into fermentable sugars and converted to bioethanol by natural microorganims. However, the conventional thermal heating that delivers heat from the surface to center of a material is comparatively slow and inefficient. As a result, the longer heating time gives rise to a dramatic reduction of reducing sugars but higher content of by-products, consequently inhibiting the subsequent fermentation. In this study, acid hydrolysis with microwave-assisted heating of macroalga was conducted in a 2.45 GHz microwave oven with 800W of power. The rapid and efficient of dielectric heating effect of microwave-assisted heating could address aforementioned problem, enhance the hydrolysis process and co-produce biochar, reducing sugars and valuable chemicals. This study was set out to study the properties of biochar as a source of biofuel after macroalga was subjected to microwave-assisted hydrolysis. The hydrolysis reactions were operated at sulfuric acid concentrations of 0.1M and 0.2M, reaction temperatures of 150–170 °C and a heating time of 10 min. The produced biochars were characterized and it was found that biochar qualities were improved with increased elemental carbon content and lower ash and moisture contents. The calorific value of the biochar was intensified up to 45%, and 39% of energy yield was recovered. Apart from biochar, the concentrations of reducing sugars and by-product of hydrolysate were also determined and subsequently converted to bioethanol. The highest total reducing sugars were 51.47 g/L (74.84% yield) along with a low by-product 5-HMF of 0.20 g/L, when the biomass was treated under the conditions at 160 °C with 0.1M H2SO4. The ethanol yield obtained was 0.33 g/g, which corresponded to a 64.21% of yield. As a conclusion, acid hydrolysis with microwave-assisted acid hydrolysis has its great potential applications for the production of bioenergy, nutrient-rich biochar for soil amelioration and value-added chemicals.
format	Thesis
qualification_name	Doctor of Philosophy (PhD.)
qualification_level	Doctorate
author	Teh, Yong Yi
author_facet	Teh, Yong Yi
author_sort	Teh, Yong Yi
title	Dilute Sulfuric Acid Hydrolysis Of Red Macroalga Eucheuma Denticulatum With Microwaveassisted Heating For Biochar And Bioethanol Production
title_short	Dilute Sulfuric Acid Hydrolysis Of Red Macroalga Eucheuma Denticulatum With Microwaveassisted Heating For Biochar And Bioethanol Production
title_full	Dilute Sulfuric Acid Hydrolysis Of Red Macroalga Eucheuma Denticulatum With Microwaveassisted Heating For Biochar And Bioethanol Production
title_fullStr	Dilute Sulfuric Acid Hydrolysis Of Red Macroalga Eucheuma Denticulatum With Microwaveassisted Heating For Biochar And Bioethanol Production
title_full_unstemmed	Dilute Sulfuric Acid Hydrolysis Of Red Macroalga Eucheuma Denticulatum With Microwaveassisted Heating For Biochar And Bioethanol Production
title_sort	dilute sulfuric acid hydrolysis of red macroalga eucheuma denticulatum with microwaveassisted heating for biochar and bioethanol production
granting_institution	Universiti Sains Malaysia
granting_department	Pusat Pengajian Kejuruteraan Kimia
publishDate	2018
url	http://eprints.usm.my/50527/1/Dilute%20Sulfuric%20Acid%20Hydrolysis%20Of%20Red%20Macroalga%20Eucheuma%20Denticulatum%20With%20Microwaveassisted%20Heating%20For%20Biochar%20And%20Bioethanol%20Production.pdf
_version_	1747822040814977024

Dilute Sulfuric Acid Hydrolysis Of Red Macroalga Eucheuma Denticulatum With Microwaveassisted Heating For Biochar And Bioethanol Production

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