Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage

Storing hydrogen efficiently in condensed materials is a key technical challenge. Tremendous efforts have been given to inorganic hydrides containing B-H, Al-H and/or N-H bonds, while organic compounds with a great variety and rich chemistry in manupulating C-H and unsaturated bonds, however, are un...

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Main Author:	Tan, Khai Chen
Format:	Thesis
Language:	English
Published:	2020
Subjects:	QD241-441 Organic chemistry
Online Access:	http://eprints.usm.my/52598/1/TAN%20KHAI%20CHEN%20-%20TESIS.pdf%20cut.pdf
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id	my-usm-ep.52598
record_format	uketd_dc
spelling	my-usm-ep.525982022-05-26T02:33:18Z Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage 2020-05 Tan, Khai Chen QD241-441 Organic chemistry Storing hydrogen efficiently in condensed materials is a key technical challenge. Tremendous efforts have been given to inorganic hydrides containing B-H, Al-H and/or N-H bonds, while organic compounds with a great variety and rich chemistry in manupulating C-H and unsaturated bonds, however, are undervalued mainly because of their unfavourable thermodynamics and selectivity in dehydrogenation. Here, we developed a new family of hydrogen storage material spanning across the domain of inorganic and organic hydrogenous compounds, namely metallo-N-heterocycles, utilizing the electron donating nature of alkali or alkaline earth metals to tune the strengths of C-H, C-N and C-C bonds of N-heterocyclic molecules to be suitable for hydrogen storage in terms of thermodynamic and kinetic properties. 2020-05 Thesis http://eprints.usm.my/52598/ http://eprints.usm.my/52598/1/TAN%20KHAI%20CHEN%20-%20TESIS.pdf%20cut.pdf application/pdf en public masters Universiti Sains Malaysia Pusat Pengajian Sains Kimia (School of Chemical Sciences)
institution	Universiti Sains Malaysia
collection	USM Institutional Repository
language	English
topic	QD241-441 Organic chemistry
spellingShingle	QD241-441 Organic chemistry Tan, Khai Chen Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage
description	Storing hydrogen efficiently in condensed materials is a key technical challenge. Tremendous efforts have been given to inorganic hydrides containing B-H, Al-H and/or N-H bonds, while organic compounds with a great variety and rich chemistry in manupulating C-H and unsaturated bonds, however, are undervalued mainly because of their unfavourable thermodynamics and selectivity in dehydrogenation. Here, we developed a new family of hydrogen storage material spanning across the domain of inorganic and organic hydrogenous compounds, namely metallo-N-heterocycles, utilizing the electron donating nature of alkali or alkaline earth metals to tune the strengths of C-H, C-N and C-C bonds of N-heterocyclic molecules to be suitable for hydrogen storage in terms of thermodynamic and kinetic properties.
format	Thesis
qualification_level	Master's degree
author	Tan, Khai Chen
author_facet	Tan, Khai Chen
author_sort	Tan, Khai Chen
title	Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage
title_short	Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage
title_full	Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage
title_fullStr	Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage
title_full_unstemmed	Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage
title_sort	development of hybrid organic-inorganic hydride for reversible hydrogen storage
granting_institution	Universiti Sains Malaysia
granting_department	Pusat Pengajian Sains Kimia (School of Chemical Sciences)
publishDate	2020
url	http://eprints.usm.my/52598/1/TAN%20KHAI%20CHEN%20-%20TESIS.pdf%20cut.pdf
_version_	1747822197142978560

Development Of Hybrid Organic-Inorganic Hydride For Reversible Hydrogen Storage

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