Optimization Of Boron-Based Nanolubricant For Diesel Engine

Wear and friction are unavoidable in engineering application nowadays. One of common solution to overcome these problems is by using lubricant which can reduce this friction and wear to a minimum level for promising to a better efficiency. The purposes of this study were to investigate the effect of...

Full description

Saved in:
Bibliographic Details
Main Author: Abdullah, Muhammad Ilman Hakimi Chua
Format: Thesis
Language:English
English
Published: 2016
Subjects:
Online Access:http://eprints.utem.edu.my/id/eprint/18517/1/Optimization%20Of%20Boron-Based%20Nanolubricant%20For%20Diesel%20Engine%2024%20Pages.pdf
http://eprints.utem.edu.my/id/eprint/18517/2/Optimization%20Of%20Boron-Based%20Nanolubricant%20For%20Diesel%20Engine.pdf
Tags: Add Tag
No Tags, Be the first to tag this record!
id my-utem-ep.18517
record_format uketd_dc
institution Universiti Teknikal Malaysia Melaka
collection UTeM Repository
language English
English
topic T Technology (General)
TJ Mechanical engineering and machinery
spellingShingle T Technology (General)
TJ Mechanical engineering and machinery
Abdullah, Muhammad Ilman Hakimi Chua
Optimization Of Boron-Based Nanolubricant For Diesel Engine
description Wear and friction are unavoidable in engineering application nowadays. One of common solution to overcome these problems is by using lubricant which can reduce this friction and wear to a minimum level for promising to a better efficiency. The purposes of this study were to investigate the effect of boron based nanolubricant on the tribological mechanism and engine performance. Design of Experiment (DOE) was constructed using the Taguchi method, which consists of L9 orthogonal arrays. The optimal design parameters were determined and indicated which of these design parameters are statistically significant for obtaining a low Coefficient of Friction (COF) with hexagonal boron nitride (hBN) and/or alumina (Al2O3) nanoparticles, dispersed in conventional diesel engine oil (SAE 15W40) as optimized nano-oil. Tribological testing was conducted using a four-ball tester according to ASTM standard D4172 procedures. The optimized nano-oil was physco-chemical characterised and the effect of dilution by biodiesel (B100) were tested before undergo for engine performance test. The optimized nano-oil was tested using AIRMAN YANMAH YX2500CXA single cylinder diesel engine which coupled with 20 horse power eddy current dynamometer. The engine performance, emission and fuel consumption testing were conducted and recorded by using DynoMite 2010 software parallel with emission analyser and fuel measurement. From analysis of Signal-to-Noise (S/N) ratio and Analysis of Variance (ANOVA), COF and wear scar diameter reduced significantly by dispersing several concentrations of hBN nanoparticles in conventional diesel engine oil, compared to without nanoparticles and with Al2O3 nanoparticle additive. Contribution of 0.5 vol.% of hBN and 0.3 vol.% of oleic acid, as a surfactant, can be an optimal composition additive in conventional diesel engine oil, to obtain a lower COF. In addition, the predicted value of COF by utilizing the levels of the optimal design parameters (0.5 vol.% hBN, 0.3 vol.% surfactant), as made by the Taguchi optimization method, was consistent with the confirmation test (average value of COF = 0.07215), which fell within a 95% Confidence Interval (CI). The optimized nano-oil shown an improvement in viscosity index where it showed a 3% better VI (Viscosity Index) reading compared to the conventional engine oil in advanced the COF obtained by 20% diluted nano-oil is still maintained in lower condition compared to diluted conventional engine oil which indicated that, dilution of optimized nano-oil did not affect the detergency of the lubricant. Result of engine performance shows that, the torque and power of conventional engine oil containing hBN nanoparticle are improved approximately 12.86% and 9.1% compared with conventional engine oil. The Brake Specific Fuel Consumption (B.S.F.C) shows significant efficiency approximately 13~32% and the gas emission of CO2 and HC reduce approximately 27.5% and 5.27%. As conclusion the damage of the material due to adhesive wear type with intensive plastic deformation was less pronounced tested by optimized nano-oil.
format Thesis
qualification_name Doctor of Philosophy (PhD.)
qualification_level Doctorate
author Abdullah, Muhammad Ilman Hakimi Chua
author_facet Abdullah, Muhammad Ilman Hakimi Chua
author_sort Abdullah, Muhammad Ilman Hakimi Chua
title Optimization Of Boron-Based Nanolubricant For Diesel Engine
title_short Optimization Of Boron-Based Nanolubricant For Diesel Engine
title_full Optimization Of Boron-Based Nanolubricant For Diesel Engine
title_fullStr Optimization Of Boron-Based Nanolubricant For Diesel Engine
title_full_unstemmed Optimization Of Boron-Based Nanolubricant For Diesel Engine
title_sort optimization of boron-based nanolubricant for diesel engine
granting_institution Universiti Teknikal Malaysia Melaka
granting_department Faculty of Mechanical Engineering
publishDate 2016
url http://eprints.utem.edu.my/id/eprint/18517/1/Optimization%20Of%20Boron-Based%20Nanolubricant%20For%20Diesel%20Engine%2024%20Pages.pdf
http://eprints.utem.edu.my/id/eprint/18517/2/Optimization%20Of%20Boron-Based%20Nanolubricant%20For%20Diesel%20Engine.pdf
_version_ 1747833930717855744
spelling my-utem-ep.185172021-10-08T13:32:30Z Optimization Of Boron-Based Nanolubricant For Diesel Engine 2016 Abdullah, Muhammad Ilman Hakimi Chua T Technology (General) TJ Mechanical engineering and machinery Wear and friction are unavoidable in engineering application nowadays. One of common solution to overcome these problems is by using lubricant which can reduce this friction and wear to a minimum level for promising to a better efficiency. The purposes of this study were to investigate the effect of boron based nanolubricant on the tribological mechanism and engine performance. Design of Experiment (DOE) was constructed using the Taguchi method, which consists of L9 orthogonal arrays. The optimal design parameters were determined and indicated which of these design parameters are statistically significant for obtaining a low Coefficient of Friction (COF) with hexagonal boron nitride (hBN) and/or alumina (Al2O3) nanoparticles, dispersed in conventional diesel engine oil (SAE 15W40) as optimized nano-oil. Tribological testing was conducted using a four-ball tester according to ASTM standard D4172 procedures. The optimized nano-oil was physco-chemical characterised and the effect of dilution by biodiesel (B100) were tested before undergo for engine performance test. The optimized nano-oil was tested using AIRMAN YANMAH YX2500CXA single cylinder diesel engine which coupled with 20 horse power eddy current dynamometer. The engine performance, emission and fuel consumption testing were conducted and recorded by using DynoMite 2010 software parallel with emission analyser and fuel measurement. From analysis of Signal-to-Noise (S/N) ratio and Analysis of Variance (ANOVA), COF and wear scar diameter reduced significantly by dispersing several concentrations of hBN nanoparticles in conventional diesel engine oil, compared to without nanoparticles and with Al2O3 nanoparticle additive. Contribution of 0.5 vol.% of hBN and 0.3 vol.% of oleic acid, as a surfactant, can be an optimal composition additive in conventional diesel engine oil, to obtain a lower COF. In addition, the predicted value of COF by utilizing the levels of the optimal design parameters (0.5 vol.% hBN, 0.3 vol.% surfactant), as made by the Taguchi optimization method, was consistent with the confirmation test (average value of COF = 0.07215), which fell within a 95% Confidence Interval (CI). The optimized nano-oil shown an improvement in viscosity index where it showed a 3% better VI (Viscosity Index) reading compared to the conventional engine oil in advanced the COF obtained by 20% diluted nano-oil is still maintained in lower condition compared to diluted conventional engine oil which indicated that, dilution of optimized nano-oil did not affect the detergency of the lubricant. Result of engine performance shows that, the torque and power of conventional engine oil containing hBN nanoparticle are improved approximately 12.86% and 9.1% compared with conventional engine oil. The Brake Specific Fuel Consumption (B.S.F.C) shows significant efficiency approximately 13~32% and the gas emission of CO2 and HC reduce approximately 27.5% and 5.27%. As conclusion the damage of the material due to adhesive wear type with intensive plastic deformation was less pronounced tested by optimized nano-oil. UTeM 2016 Thesis http://eprints.utem.edu.my/id/eprint/18517/ http://eprints.utem.edu.my/id/eprint/18517/1/Optimization%20Of%20Boron-Based%20Nanolubricant%20For%20Diesel%20Engine%2024%20Pages.pdf text en public http://eprints.utem.edu.my/id/eprint/18517/2/Optimization%20Of%20Boron-Based%20Nanolubricant%20For%20Diesel%20Engine.pdf text en validuser https://plh.utem.edu.my/cgi-bin/koha/opac-detail.pl?biblionumber=100398 phd doctoral Universiti Teknikal Malaysia Melaka Faculty of Mechanical Engineering 1. Abdollah, M.F., Mazlan, M.A.A., Amiruddin, H., Tamaldin, N., 2013. Frictional Behavior of Bearing Material under Gas Lubricated Conditions. Procedia Engineering, 68, pp.688-693. 2. Annam, R.A., Nurshaun, S., and Megesh, P., 2014. Optimization of algal methyl esters using RSM and evaluation of biodiesel storage characteristics. Bioresources and Bioprocessing, 1 (19). 3. ASTM D 4172, 2010. Standard Test Method for Wear Preventive Characteristics of Lubricating Fluid (Four-Ball Method). 4. ASTM D2270-04, 2011. Standard Practice for Calculating Viscosity Index From Kinematic Viscosity at 40 and 100°C. 5. ASTM D664-11a, 2010. Standard Test Method for Acid Number of Petroleum Products by Potentiometric Titration. 6. Bartels, T., Lubricants, 5. Gear lubrication Oils. Ullmann’s Encyclopedia of Industrial chemistry, ISBN: 9783527306732, DOI: 10.1002/14356007. 7. Bas, H., and Karabacak, Y.E., 2014. Investigation of the effects of boron additives on the performance of engine oil. Tribology Transections, 57 (4), pp.740–748. 8. Bastian, E.L.H., 1968. LubrEng 25 (7), pp.278. 9. Belin, M, Martin, J.M., and Mansot, J.L., 1987. Role of iron in the amorphization process in friction-induced phosphate glasses. Journal de Physique, 48 (C9), pp. 1147-53. 10. Bell, J.C., Delargy, K.M., and Seeney, A.M., 1992. The removal of substrate material through thick zinc dithiophosphate antiwear films. Tribology series, wear particles: from the cradle to the grave. Amsterdam. Elsevier, (21), pp. 387-96. 11. Bowman, W., and Stachowiak, G., 1996. Determining the oxidation stability of lubricating oils using sealed capsule differential scanning calorimetry (SCDSC). Tribology International, 29, pp.27-34. 12. Brown, H.M., 2013. Optimization of the Production of Lubricating Oil fromRe-Refined Used Lubricating Oil using Response Surface Methodology. ARPN Journal of Engineering and Applied Sciences, 8 (9), pp.749-756. 13. Chang, H., Li, Z.Y., Kao, M.J., Huang, K.D., and Wu, H.M., 2010. Tribological property of TiO2 nanolubricant on piston and cylinder surfaces, Journal of Alloys and Compounds, 495 (2), pp.481-484. 14. Chen, S., Liu, W., and Yu. L., 1998. Preparation of DDP-Coated PbS Nanoparticles and Investigation of the Antiwear Ability of the Prepared Nanoparticles as Additive in Liquid Paraffin. Wear, 218, pp.153-158. 15. Chhowalla, M., and Gehan, A.J.A., 2000. Thin films of fullerene-like MoS2 nanoparticles with ultra-low friction and wear. Nature, 407, pp.164-167. 16. Chinas-Castillo, F., and Spikes, H.A., 2003. Mechanism of Action of Colloidal Solid Dispersions. Journal of Tribology, 125, pp.552-557. 17. Chunli, Z., Shengmao, Z., Laigui, Y., Zhijun, Z., Zhishen, W., and Pingyu, Z., 2012. Preparation and tribological properties of water-soluble copper/silica nanocomposite as a water-based lubricant additive. Journal Applied Surface Science, 259, pp.824-830. 18. CNGenerator, 2015. [online] Available at: http://www.cngenerator.com/product/air_cooled_diesel_engine.php [Accessed on 26 October 2014]. 19. Costa, L.M., Ferreire, S.L.C., Nogueira, A.R.A., and Joaquim, A.N., 2005. Use of factorial design for optimization of microwave-assisted digestion of lubricating oil. Journal of the Brazilian Chemical Society, 16 (6A), pp.1269-1274. 20. Dowson, D., 1979. History of Tribology. New York: Longmans Green. 21. David. J.M., Brookfield Engineering Laboratories, Inc., 2007. United State. Pat. US20060075805. 22. David, W.J., and John, E.H., 2013. Phosphate Esters, Thiophosphate Esters and Metal Thiophosphates as Lubricant Additives. Lubricants, 1, pp. 132-148. 23. “Dispersing process.” [Online]. Available at: http://www.inkline.gr/inkjet/newtech/tech/dispersion/ [Accessed: 01-Jan-2015]. 24. Duzeukoglu, H., and Sahin, O.S., 2010. Investigation of Wear Performance on Canola Oil Containing Boric Acid under Boundary Friction Condition. Tribology Transection, 54. pp.57-61. 25. Evans Analytical Group., 2015. Materials Characterization: Fourier Transform Infrared Spectroscopy, FTIR Analysis. [online] Available at: http://www.eag.com/mc/fourier-transform-infrared-spectroscopy.html [Accessed on 20 October 2013]. 26. Ghani, J.A., Choudhury, I.A., and Masjuki, H.H., 2004. Tool Life And Wear Mechanism Of P10 Tin Carbide Tool In High Speed End Milling Operations. Journal Industrial Technology, 13 (1), pp.13-25. 27. Guangbin, Y., Jinfeng, Z., Shengmao, Z., Laigui, Y., Pingyu, Z., and Baoli, Z., 2013. Preparation of triazine derivatives and evaluation of their tribological properties as lubricant additives in poly-alpha olefin. Tribology International, 62 (315), pp.133-143. 28. Hidalgo. A., Makarov, V., Morell, G., and Weiner, B.R., 2013. High-Yield Synthesis of Cubic and Hexagonal Boron Nitride Nanoparticles by Laser Chemical Vapor Decomposition of Borazine. Dataset Papers in Nanotechnology, 2013, pp.5. 29. Hamrock, B.J., and Dowson, D., 1981. Ball Bearing Lubrication: The Elastohydrdynamics of Elliptical Contacts., New York: Wiley. 30. Hannu. J., 2012. Crankcase Ventilation. [online] Available at: https://www.dieselnet.com/tech/engine_crank.php [Accessed on 1 November 2014]. 31. Harris, J.W., and Stocker, H., 1998. Spherical Segment. Handbook of Mathematics and Computational Science. New York; Springer-Verlag, pp.107. 32. Hasan, B., and Yunus, E.K., 2014. Investigation of the Effects of Boron Additives on the performance of engine oil. Tribology Transections, DOI: 10.1080/10402004.2014.909549. 33. Herdan, J.M., 2000. Friction modifiers in engine and gear oils. Lubricant. Science, 12 (3), pp.265-276. 34. Holmes, L., 1976. Oldhams New Motor Manual ED; Hamlyn Publishing Group 35. Hu, Z., Lai, R., Lou, F., Wang, L., Chen, Z., Chen, G., and Dong, J., 2002. Preparation and Tribological Properties of nanometer Magnesium Borates as Lubricating Oil Additives. Wear, 252, pp.370-374. 36. Huang, H., Tu, J., Gan, L., and Li, C. 2006. An investigation on tribological properties of Graphite Nanosheets as Oil Additive. Wear, 261, pp.140-144. 37. Husnawan, M., Saifullah, M.G., and Masjuki, H.H., 2007. Development of friction force model for mineral oil basestock containing palm olein and antiwear additive. Tribology International, 40, pp.74-81. 38. Hsiao, Y.C., Chen. W., Hsu, and Jen, F.L., 2010. Scuffing mechanism during oil-lubricated block-on-ring test with diamond nanoparticles as oil additive. Wear, 268(11-12), pp.1423-1433. 39. Hwang, Y., Lee, C., Choi, Y., Cheong, S., Kim, D., Lee, K., Lee, J., and Kim, S.H., 2011. Effect of the Size and Morphology of Particles Dispersed in Nano-Oil on Friction Performance Between Rotating Discs. Journal of Mechanical Science and Technology. 25, pp.2853-2857. 40. Impex Canada, M.K., 2008. Material Safety Data Sheet: Uses of Hexagonal Boron Nitride (hBN). 41. Index of Hartford., 2012. Lubricant: picture. [online] Available at: http://www.ewp.rpi.edu/hartford/~ernesto/F2012/FWM/Pics/Lubrication [Accessed on 30 August 2013]. 42. Ishiki, K., and Urabe, M., 2000. A study of abnormal wear in power cylinder of diesel engine with EGR-wear mechanism of soot contaminated in lubricating oil. SAE Technical Paper, No. 2000-01-0925. 43. Jim Fitch., 2014. Machinery lubrication: The Enduring Flash Point Test. [online] Available at: http://www.machinerylubrication.com/Read/19/flash-point-test [Accessed on 15 October 2013]. 44. Johnson, D.R., and Diamond, S., 1999. Heavy vehicle propulsion materials: recent progress and future plans. SAE Technical Paper, No. 1999-01-2255. 45. Julian. E., 2012. Brake Specific Fuel Consumption. [online] Available at: http://www.autospeed.com.au/cms/article.html?&A=112611 [Accessed on 15 October 2014]. 46. Kalam, M.A., Masjuki, H.H., Shahabuddin, M, and. Mofijur, M., 2012. Tribological characteristics of amine phosphate and octylated/butylated diphenylamine additives infused bio-lubricant, Energy Education Science Tech-A, 30 (1), pp.123-136. 47. Kalam, M.A., Masjuki, H.H., Shahabuddin, M., and Mofijur, M., 2012. Tribological characteristics of amine phosphate and octylated/butylated diphenylamine additives infuse bio-lubricant. Energy Education Science and Technology Part A: Energy Science and Research, 30 (1), pp.123-136. 48. Kennedy, F.E., Booser, E.R.,and Wilcock, D.F., 2005. Tribology, Lubrication and Bearing Design. The CRC Handbook of Mechanical Engineering. 2nd edition, CRC Press, Boca Raton, Fla, section 3, pp.129-170. 49. Kenneth, H., Peter, A., and Ali, E., 2012. Global energy consumption due friction in passenger cars. Tribology International, 47, pp. 221-234. 50. Kondo, Y., Koyama, T., and Sasaki, S., 2013. Tribological properties of Ionic Liquids., Japan: Materials Science Intecth 51. Kotrba, R., 2009. Biodiesel Magazine: Engine oil additive addresses biodiesel fuel dilution. [online] Available at: http://biodieselmagazine.com/articles/3605/engine-oil-additive-addresses-biodiesel-fuel-dilution. [Access on 30 March 2015]. 52. Kus. R., 2011. The effect of raw corn oil and diesel fuel mixture on engine performances and emissions. Energy Education Science Tech-A. 28, pp.469-474. 53. Lee, K., Hwang, Y., Cheong, S., Choi, Y., Kwon, L., Lee, J., and Kim, S.H., 2009. Understanding the Role of Nanoparticles in Nano-Oil Lubrication. Tribology Letter, 35, pp.127-131. 54. Li, W., Zheng, S., and Cao, B., 2011. Friction and wear properties of ZrO2/SiO2 composite nanoparticles. Journal of Nanoparticle Research, 13 (5), pp. 2129-2137. 55. Liu, G., Li, X., Qin, B., Xing, D., Guo, Y., and Fan, R., 2004. Investigation of the Mending Effect and Mechanism of Copper Nano-Particles on a Tribologically Stressed Surface. Tribology Letter, 17, pp.961-966. 56. Liu, H., Bai, M., and Qu., 2012. The Impact of Oil-Based Diamond Nanofluids on Diesel Engine Performance. Proceeding of the FISITA 2012 World Automotive Congress, 190, pp.1313-1319. 57. Macian, V., Tormos, B., Ruiz, S., Ramirez Roa, L. et al., 2014. In-Use Comparison Test to Evaluate the Effect of Low Viscosity Oils on Fuel Consumption of Diesel and CNG Public Buses. SAE Technical Paper, No. 2014-01-2794. 58. Mahadevi, D., and Manikandan, M., 2014. Modelling and Parametric Optimization using Factorial DesignApproach of Tig Welding of AZ61 Magnesium Alloy. International Journal of Mechanical Engineering (SSRG-IJME), 1 (1), pp.18-22. 59. Marcos, A.B., Ricardo, E.S., Eliane, P.O., Leonardo, S.V., Luciane, A.E., 2008. Response surface methodology (RSM) as a tool for optimization in analytical chemistry. Journal of Talanta, 76 (5), pp.965-977. 60. Mark, A., and Kedzierski., 2013. Viscosity and density of aluminum oxide nanolubricant. International Journal of Refrigeration, 36 (4), pp.1333-1340. 61. Martin, J.M., 1997. Lubricant additives and the chemistry of rubbing surfaces: Metal dithiophosphatestriboreaction films revisited. Journal. Tribology, 42, pp.9. 62. Martin, J.M., 1999. Antiwear mechanisms of zinc dithiophosphate: A chemical hardness approach. Tribology letter, 6, pp.1- 8. 63. Martin, J.M., Belin, M., Mansot, J.L., 1986. An EXAFS study: Friction induced amorphization with ZDDP. ASLE Transactions, 49 (4), pp. 523-531. 64. Martin, J.M., Grossiord, C., Le Mogne T., Igarashi, J., 2000. Transfer films and friction under boundary lubrication. Wear, 245, pp.107-15. 65. Martin, J.M., Grossiord, C., Lemogne, T., Bec, S., and Tonck, A., 2001. The two layers structure of Zndtptribofilm part 1: AES, XPS and XANES analyses. Tribology International, 31 (10), pp. 627-44. 66. Martin, J.M., Mansot, J.L., Berbezier, I., and Belin, M., 1986. Microstructural aspects of lubricated mild wear with zinc dithiophosphate. Wear, 107, pp. 355-366. 67. Martin, J.M., Mansot, J.L., Berbezier, I., and Dexpert, H., 1984. The nature and origin of wear particle from boundary lubrication with ZDDP. Wear, 93 (2), pp.117-126. 68. Motor Oil Degradation, 2006. Technical Article No. 68, Publication of Lubricant Engineers, Lubrication Engineers Inc, Taxas USA. 69. Metrohm, 1995.DMS Titrino 716: Instructions for Use. Herisau, Switzerland. 70. Norbaria,S., Kian, H.K., Beverly, K., and Suhaimi, M.Y., 2013. Effect of Fuel Dilution in the Lubricant on Wear of Cam & Tappet. International Journal of Chemical and Environmental Engineering, 4 (2). 71. NREL., 2009. National Renewable Energy Laboratory: Biodiesel Handling and Use Guide. [online] Available at: http://www.nrel.gov/vehiclesandfuels/pdfs/43672.pdf [Accessed on 30 August 2013]. 72. Parash., Kalita., Ajay., Malshe, P., Arun, S., Kumar, V.G., Yoganath, T., and Gurumurthy., 2012. Study of specific energy and friction coefficient in minimum quantity lubrication grinding using oil-based nanolubricants. Journal of Manufacturing Processes, 14 (2), pp.160-166. 73. Pietm, L., 2009. A review on Grease Lubrication in Rolling Bearings. Tribology Transections, 52, pp.470-480. 74. Pixshark, 2014. Image galleries [online] Available at: http://pixshark.com/al2o3-structure.htm [Accessed on 19 November 2014]. 75. Pradeep, D., and Sorte, M.B., 2013. Optimization of Welding Parameters UsingTaguchi Method for Submerged Arc Welding On Spiral Pipes. International Journal of Recant Technology and Engineering (IJRTE), 2 (5), pp.2277-3878. 76. Pradeep, M., Michael, N., Sudeep, P., Ingole., Satish, V., Kailas., and Michael, R.L., 2014. Tribology for Scientists and Engineers: From Basics to Advanced Concepts, 2013th ed., Springer. 77. Press Release, 2009. Success in Trial Manufacture of Far-UV Surface Plane Emitting Device based on h-BN [online] Available at: www.nims.go.jp/eng/news/press/2009/09/p200909210.html [Accessed on 19 November 2014]. 78. Qingdong, Z., Michael, R., Zhao, Z., 2004. Study of lubricants and their effect on the anti-corrosion performance as temporarily protective oil coatings. Journal Surface and Coatings Technology, 185 (2-3), pp.234-239. 79. Qiu, S., Dong, J., Chen. G., 1999. Preparation of Ni nanoparticles and evaluation of their tribological performance as potential additives in oils. Journal of Tribology, 123, pp.441–443. 80. Qiu, S., Zhou, Z., Dong, J., and Chen G., 2001. Preparation of Ni nanoparticles and evaluation of their tribological performance as potential additives in oils. Journal Tribology, 123, pp.441. 81. Quazi, T.Z., Pratik, M., and Vipul, S., 2013. A Case Study of Taguchi Method in the Optimization of Turning Parameters. International Journal of Emerging Technology and Advanced Engineering, 3 (2), pp.616-626. 82. Rahman, M.Q., Chuah, K.S., Macdonald. E.C.A., Trusler, J.P.M., and Ramaesh K., 2012. The effect of pH, dilution, and temperature on the viscosity of ocular lubricants-shift in rheological parameters and potential clinical significance. Nature, Eye (26), pp.1579-1584. 83. Raimoindi, A.A., and Szeri, A.Z., 1984. Journal and Thrust Bearing, Handbook of lubrication. CRC Press, Boca Raton. 2, pp.413-462. 84. Raj, F.R.M.S., and Sahayaraj, J.W., 2010. A Comparative Study over Alternative Fuel (Biodiesel) for Environmental Friendly Emission. Recent Advances in Space Technology Services and Climate Change (RSTSCC), pp.80-86. 85. Rama, R.S., and Padmanabhan, G., 2012. Application of Taguchi methods and ANOVA in optimization ofprocess parameters for metal removal rate in electrochemicalmachining of Al/5%SiC composites. International journal of Engineering Research and Applications (IJERA), 2 (3), pp.192-197. 86. Ranjit, K. R., 2001. Design of experiments using the taguchi approach, Ney work: John Wiley & Sons, Inc. 87. Repco., 1972. Repco Engine Service Manual. 88. Rico, E. F., Minondo, I., and Cuervo, D. G., 2007. The effectiveness of PTFE nanoparticle powder as an EP additive to mineral base oils. Wear, 262, pp.1399-1406. 89. Ross, P.J., 1996. Taguchi techniques for quality engineering, Singapore: McGraw-Hill International Editions. 90. Sam, G., Balla, S., Vishaal, G., Mridul, G., 2007. Effect of diesel soot on lubricant oil viscosity. Tribology International, 40 (5), pp.809-818. 91. Sanjay, K.M., Pradhan, M.K., and Hargovind, S., 2013. Optimization of EDM Parameters Using Integrated Approach of RSM, GRA and Entropy Method. International Journal of Applied Research in Mechanical Engineering (IJARME), 3 (1), pp.2231-6950. 92. Singh, G., Graves R.L., Storey, J.M., Partridge, W.P., Thomas, J.F., Penetrante, B.M., Brusasco, R.M., Merritt, B.T., Vogtlin, G.E., Aardahl, C.L., Habeger, C.F., and Balmer, M.L., 2000. Emission control research to enable fuel efficiency. SAE Paper, No. 2000-01-2198. 93. Smith, O., Priest, M., Taylor, R.I., Price, R., Cantlay, A., and Coy, R.C., 2006. Simulated fuel dilution and friction-modifier effects on piston ring friction. Journal of Engineering Tribology, 220 (3), pp.181-189. 94. Song, B.H., and Choi, Y.H., 2008. Investigation of variations of lubricating oil diluted by post-injected fuel for the regeneration of CDPF and its effects on engine wear. Journal of Mechanical Science and Technology, 22, pp.2526-2533. 95. Spikes, H., 2004. The history and mechanisms of ZDDP. Tribology Letter, 17 (3), pp. 469-89. 96. Stachowiak, G.W., and Batchelor A.W., 2005. Engineering Tribology. 97. Stipanovic, A.J., and Schoonmaker, J.P., 1993. The impact of organomolybdenum compounds on the frictional characteristics of crankcase engine oils. SAE Technical Paper, No. 932779. 98. Tao, X., Jiazheng, Z., and Kang. X., 1996. The Ball-Bearing Effect of Diamond Nanoparticles as an Oil Additive. J. Phys. D: Appl. Phy,. 29, pp.2932. 99. Vanhulsel, A., Velasco, F., Jacobs, R., Eersels, L., Havermans, D., Roberts, E.W., Sherrington, I., Anderson, M.J., and Gaillard, L., 2006. DLC solid lubricant coatings on ball bearing for space applications. Tribology International, 40 (7), pp.1186-1194. 100. Waara, P., Hannu, J., Norrby, T., and Byheden, A., 2001. Additive influence on wear and friction performance of environmentally adapted lubricants. Tribology International, 34, pp.547-556. 101. Wallfahrer, U., 1999. Polymer esters and their synergy with ZDDP: a possibility to reduce ZDDP content in lubricant. 9th International colloquium, ecological and economical aspects of tribology, Esslingen, 11 (14), pp.1-10. 102. Wallfahrer, U., and Bowen, L., 1997. Low ZDDP: High performance semisynyhetic automotive engine oils using polymer esters as an antiwear booster. LubrEng, 53, pp.23-8. 103. Wattrus, M., 2013. Fuel Property Effects on Oil Dilution in Diesel Engines, SAE International. Journal Fuels Lubricant, 6(3), pp.794-806. 104. William, J., Rene, B., Paul, S., and David, M., 2011. The influence of the lubricant film on the stiffness and damping characteristics of a deep groove ball bearing. Mechanical Systems and Signal Processing, 42 (1-2), pp. 335-350. 105. Wills, J.G., 1980. Lubricant fundamentals, New York: Marcel Dekker. 106. Wolfram Mathworld., 2013. Spherical Cap [online] Available at: http://mathworld.wolfram.com/SphericalCap.html [Accessed on 23 December 2013]. 107. Wu, Y.Y., Tsui, W.C., and Liu, T.C., 2007. Experimental Analysis of Tribological Properties of Lubricating Oils with Nanoparticle Additives. Wear, 262, pp.819-825. 108. Xiaodong, Z., Xun, F., Huaqiang, S., and Zhengshui, H., 2007. Lubricating Properties of Cyanex 302-Modified Mos2 Microspheres in Base Oil 500SN. Lubrication Science, 19, pp.71-79. 109. Yu, H., Xu, Y., Shi, P., Wang, H., Zhao, Y., Xu, B., and Bai, Z., 2010. Tribological Behaviours of Surface-Coated Serpentine Ultrafine Powders as Lubricant Additive. Tribology International, 43, pp.667-675. 110. Yuan, X., Liu, X., and Zuo, Jian., 2015. The development of new energy vehicles for a sustainable future: A review. Renewable and Sustainable Energy Reviews, 42, pp.298-305. 111. Zhang M, Wang X, Liu W, et al. Performance and anti-wear mechanism of Cu nanoparticles as lubricating oil additives. Industrial Lubrication and Tribology 2009; 61 (6): 311-318. 112. Zhang, C., 2005. Research on thin film lubrication: state of the art. Tribology International, 38 (4), pp.443-448. 113. Zhang, C., Luo, J., Huang, Z., 2005. Analysis on mechanism of thin film lubrication. Chinese Science Bulletin. 50 (22), pp.2645-2649. 114. Zhang, M., Wang, X., Fu, X., and Xia, Y., 2009. Perofrmance and Antiwear Mechanism of CaCO3 Nanoparticles as a Green Additive in Poly-Alpha-Olefin. Tribology International, 42, pp.1029-1039. 115. Zhang, M., Wang, X., Liu, W., and Fu, X., 2009. Performance and anti-wear mechanism of Cu nanoparticles as lubricating oil additives. Industrial Lubrication and Tribology, 61 (6), pp. 311-318. 116. Zhang, Z.F., Liu, W.M., and Xue, Q.J., 2001. The Tribological Behaviors of Succinimide-Modified Lanthanum Hydroxide Nanoparticles Blende with Zinc Dialkyldithiophosphate as Additives in Liquid Paraffin. Wear, 248, pp.48-54. 117. Zhao, C., Jiao,Y., Chen, Y.K., and Ren, G., 2014. The Tribological Properties of Zinc Borate Ultrafine Powder as a Lubricant Additive in Sunflower Oil. Tribology Transactions, 57, pp.425-434. 118. Zulkifli, N.W.M., Kalam, M.A., and Masjuki, H.H., 2014. The effect of palm oil trimethylolpropane ester on extreme pressure lubrication. Journal of Engineering Tribology, DOI: 10.1177/1350650113500945.