Synthesis and mechanical analysis of electroconductive high density polyethylene polyanilinedodecylbenzenesulfonic acid/alumina composite

Polyaniline (PANI) based composites have become of great interest in supercapacitor electrode application due to its high conductivity (13.37 Scm-1) and capacitance (501.31 Fg-1).Some researchers have established excellent capacitance of PANI based electrodes.Yet pseudo-capacitive nature of the PANI...

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Main Author:	Mustaffa, Nurul Akmil
Format:	Thesis
Language:	English English
Published:	2018
Subjects:	Q Science (General) QD Chemistry
Online Access:	http://eprints.utem.edu.my/id/eprint/23385/1/Synthesis%20And%20Mechanical%20Analysis%20Of%20Electroconductive%20High%20Density%20Polyethylene%20Polyanilinedodecylbenzenesulfonic%20Acid%20Alumina%20Composite.pdf http://eprints.utem.edu.my/id/eprint/23385/2/Synthesis%20and%20mechanical%20analysis%20of%20electroconductive.pdf
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id	my-utem-ep.23385
record_format	uketd_dc
institution	Universiti Teknikal Malaysia Melaka
collection	UTeM Repository
language	English English
advisor	Mohd Abid, Mohd Asyadi Azam
topic	Q Science (General) QD Chemistry
spellingShingle	Q Science (General) QD Chemistry Mustaffa, Nurul Akmil Synthesis and mechanical analysis of electroconductive high density polyethylene polyanilinedodecylbenzenesulfonic acid/alumina composite
description	Polyaniline (PANI) based composites have become of great interest in supercapacitor electrode application due to its high conductivity (13.37 Scm-1) and capacitance (501.31 Fg-1).Some researchers have established excellent capacitance of PANI based electrodes.Yet pseudo-capacitive nature of the PANI electrodes causes swelling, shrinking and cracking during doping/dedoping of charged ions that have resulted in poor cycle stability thus limits its application.This study aims to enhance the PANI properties to be used as a supercapacitor electrode. PANI doped with dodecylbenzene sulfonic acid (PANI-DBSA) was synthesized through oxidative polymerization by varying concentrations of dopant (DBSA) and concurrently nano alumina (Al2O3) was synthesized and functionalized with silane.Later,high density polyethylene/PANI-DBSA/ Al2O3 (HDPE/PANI-DBSA/Al2O3) composite was fabricated via a statistical approach to optimize the level of DBSA, PANI-DBSA and nano alumina in HDPE in order to incorporate comparable mechanical strength and conductivity.The application of conductive composite of HDPE/PANI-DBSA/Al2O3 towards supercapacitor electrode performance has been verified.As the result,the DBSA doping of PANI produces the protonation of amine nitrogen atoms of PANI.This redox reaction creates charge carrier in form of bipolarons and polaron species in PANI structure thus has enhanced the conductivity of PANI. However,over-doping leads to a decrease of polaron population, due to its conversion to bi-polarons which decrease the conductivity of PANI.Afterwards,through RSM study,the recommended optimum formulation of HDPE/PANIDBSA/Al2O3 composite is made by controlling the concentration of DBSA at 2.00 mmol,composition of PANI-DBSA at 20 wt%,and composition of nano alumina at 5wt %. This recommended formulation yielded a desirability of confident level at 86.65% which is well above the accepted of 80 %.It demonstrates the improved compatibility between PANIDBSA,nano alumina and HDPE through intermolecular forces from the interactions between two organic molecules.The hydrophobic effect of the organic substitution in DBSA and silane could be linked with the free energy transfer of hydrocarbon molecules from an aqueous phase (hydrophilic substitution in PANI molecule and nano alumina surface) to a homogeneous hydrocarbon phase.As a final point,the results demonstrate the fabrication of a promising electrode material derived from HDPE filled PANI-DBSA and nano alumina particles have improved the electrochemical performance of HDPE/PANI/Al2O3║MWCNT asymmetric supercapacitors in Na2SO4,KOH,and H2SO4 aqueous electrolytes.Among the electrolytes,KOH exhibited better specific gravimetric capacitance (145.58 Fg-1) and good capacitance retention (101%) after 10,000 charge-discharge cycles.In brief,HDPE/PANI/Al2O3║MWCNT asymmetric supercapacitor has maximum energy density of 0.55 Whkg-1 with a power density of 0.33 kWkg-1.Thus,the asymmetric supercapacitor is well-suited for power storage since it has a high power density,then it can output large amounts of energy based on its volume.
format	Thesis
qualification_name	Doctor of Philosophy (PhD.)
qualification_level	Doctorate
author	Mustaffa, Nurul Akmil
author_facet	Mustaffa, Nurul Akmil
author_sort	Mustaffa, Nurul Akmil
title	Synthesis and mechanical analysis of electroconductive high density polyethylene polyanilinedodecylbenzenesulfonic acid/alumina composite
title_short	Synthesis and mechanical analysis of electroconductive high density polyethylene polyanilinedodecylbenzenesulfonic acid/alumina composite
title_full	Synthesis and mechanical analysis of electroconductive high density polyethylene polyanilinedodecylbenzenesulfonic acid/alumina composite
title_fullStr	Synthesis and mechanical analysis of electroconductive high density polyethylene polyanilinedodecylbenzenesulfonic acid/alumina composite
title_full_unstemmed	Synthesis and mechanical analysis of electroconductive high density polyethylene polyanilinedodecylbenzenesulfonic acid/alumina composite
title_sort	synthesis and mechanical analysis of electroconductive high density polyethylene polyanilinedodecylbenzenesulfonic acid/alumina composite
granting_institution	Universiti Teknikal Malaysia Melaka
granting_department	Faculty Of Manufacturing Engineering
publishDate	2018
url	http://eprints.utem.edu.my/id/eprint/23385/1/Synthesis%20And%20Mechanical%20Analysis%20Of%20Electroconductive%20High%20Density%20Polyethylene%20Polyanilinedodecylbenzenesulfonic%20Acid%20Alumina%20Composite.pdf http://eprints.utem.edu.my/id/eprint/23385/2/Synthesis%20and%20mechanical%20analysis%20of%20electroconductive.pdf
_version_	1747834046275125248
spelling	my-utem-ep.233852022-06-13T12:42:35Z Synthesis and mechanical analysis of electroconductive high density polyethylene polyanilinedodecylbenzenesulfonic acid/alumina composite 2018 Mustaffa, Nurul Akmil Q Science (General) QD Chemistry Polyaniline (PANI) based composites have become of great interest in supercapacitor electrode application due to its high conductivity (13.37 Scm-1) and capacitance (501.31 Fg-1).Some researchers have established excellent capacitance of PANI based electrodes.Yet pseudo-capacitive nature of the PANI electrodes causes swelling, shrinking and cracking during doping/dedoping of charged ions that have resulted in poor cycle stability thus limits its application.This study aims to enhance the PANI properties to be used as a supercapacitor electrode. PANI doped with dodecylbenzene sulfonic acid (PANI-DBSA) was synthesized through oxidative polymerization by varying concentrations of dopant (DBSA) and concurrently nano alumina (Al2O3) was synthesized and functionalized with silane.Later,high density polyethylene/PANI-DBSA/ Al2O3 (HDPE/PANI-DBSA/Al2O3) composite was fabricated via a statistical approach to optimize the level of DBSA, PANI-DBSA and nano alumina in HDPE in order to incorporate comparable mechanical strength and conductivity.The application of conductive composite of HDPE/PANI-DBSA/Al2O3 towards supercapacitor electrode performance has been verified.As the result,the DBSA doping of PANI produces the protonation of amine nitrogen atoms of PANI.This redox reaction creates charge carrier in form of bipolarons and polaron species in PANI structure thus has enhanced the conductivity of PANI. However,over-doping leads to a decrease of polaron population, due to its conversion to bi-polarons which decrease the conductivity of PANI.Afterwards,through RSM study,the recommended optimum formulation of HDPE/PANIDBSA/Al2O3 composite is made by controlling the concentration of DBSA at 2.00 mmol,composition of PANI-DBSA at 20 wt%,and composition of nano alumina at 5wt %. This recommended formulation yielded a desirability of confident level at 86.65% which is well above the accepted of 80 %.It demonstrates the improved compatibility between PANIDBSA,nano alumina and HDPE through intermolecular forces from the interactions between two organic molecules.The hydrophobic effect of the organic substitution in DBSA and silane could be linked with the free energy transfer of hydrocarbon molecules from an aqueous phase (hydrophilic substitution in PANI molecule and nano alumina surface) to a homogeneous hydrocarbon phase.As a final point,the results demonstrate the fabrication of a promising electrode material derived from HDPE filled PANI-DBSA and nano alumina particles have improved the electrochemical performance of HDPE/PANI/Al2O3║MWCNT asymmetric supercapacitors in Na2SO4,KOH,and H2SO4 aqueous electrolytes.Among the electrolytes,KOH exhibited better specific gravimetric capacitance (145.58 Fg-1) and good capacitance retention (101%) after 10,000 charge-discharge cycles.In brief,HDPE/PANI/Al2O3║MWCNT asymmetric supercapacitor has maximum energy density of 0.55 Whkg-1 with a power density of 0.33 kWkg-1.Thus,the asymmetric supercapacitor is well-suited for power storage since it has a high power density,then it can output large amounts of energy based on its volume. 2018 Thesis http://eprints.utem.edu.my/id/eprint/23385/ http://eprints.utem.edu.my/id/eprint/23385/1/Synthesis%20And%20Mechanical%20Analysis%20Of%20Electroconductive%20High%20Density%20Polyethylene%20Polyanilinedodecylbenzenesulfonic%20Acid%20Alumina%20Composite.pdf text en public http://eprints.utem.edu.my/id/eprint/23385/2/Synthesis%20and%20mechanical%20analysis%20of%20electroconductive.pdf text en validuser https://plh.utem.edu.my/cgi-bin/koha/opac-detail.pl?biblionumber=112874 phd doctoral Universiti Teknikal Malaysia Melaka Faculty Of Manufacturing Engineering Mohd Abid, Mohd Asyadi Azam 1. 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