Enhancement of antifouling properties using rice husk silica particles in polysulfone membrane and optimization of its operating condition
This study investigates the effects of rice husk silica (RHS) as additive in the polysulfone membrane to enhance antifouling properties in membrane separation process. The flat sheet PSf/RHS membrane was prepared via phase inversion technique. The characterization and performance test were conduc...
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my-uthm-ep.15592021-10-03T07:59:38Z Enhancement of antifouling properties using rice husk silica particles in polysulfone membrane and optimization of its operating condition 2014-06 Jamalludin, Mohd Riduan TP Chemical technology This study investigates the effects of rice husk silica (RHS) as additive in the polysulfone membrane to enhance antifouling properties in membrane separation process. The flat sheet PSf/RHS membrane was prepared via phase inversion technique. The characterization and performance test were conducted on PSf ultrafiltration membrane prepared from a different additive concentration. The thermal stability of prepared membrane was observed by using thermogravimetric analysis (TGA). The cross section area and particles distribution of additive were carried out by using the scanning electron microscope (SEM) while the surface morphology was investigated via field emission scanning electron microscope (FESEM). The surface roughness and hydrophilicity were also determined by using Atomic force microscopy (AFM) and contact angle measurement respectively. Meanwhile, the performance was evaluated in term of pure water flux (PWF), rejection and antifouling properties. The optimized of normalized flux (Jf /Jo) at different parameter filtration condition (pH, ionic strength and tranmembranepressure) was carried out by using the response surface methodology (RSM). From the analysis of SEM, FESEM and AFM, results showed that the microstructure of the membrane especially at top layer and sub layer obviously changed with the incorporation of RHS. The results also demonstrated that the mean pore size was decreased and hyrophilicity was increased as increased RHS particles in PSf membrane. The performance of the membrane was analyzed by using distilled water for permeation test and humic acid for the rejection test. The results also showed that the hydrophilic PSf/RHS membrane has significantly improved the permeation and rejection performance after the addition of RHS. The results showed that the addition of 4 wt. % RHS give the highest flux at 300.50 L/m².hour (LMH). The highest rejection was found at 3 wt. % of RHS membrane with value 98% for UV254 and 96% for TOC. The optimal value of Jf/Jo was found at 0.62 with the parameter condition pH: 6.10, ionic strength: 0.05 mol/L and transmembrane-pressure: 2.67 bars. Optimize of RSM analysis also proved that the error of model is less than 0.05% which indicates that the model is significant. 2014-06 Thesis http://eprints.uthm.edu.my/1559/ http://eprints.uthm.edu.my/1559/1/24p%20MOHD%20RIDUAN%20JAMALLUDIN.pdf text en public http://eprints.uthm.edu.my/1559/2/MOHD%20RIDUAN%20JAMALLUDIN%20COPYRIGHT%20DECLARATION.pdf text en staffonly http://eprints.uthm.edu.my/1559/3/MOHD%20RIDUAN%20JAMALLUDIN%20WATERMARK.pdf text en validuser mphil masters Universiti Tun Hussein Malaysia Fakulti Kejuruteraan Mekanikal dan Pembuatan |
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TP Chemical technology |
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TP Chemical technology Jamalludin, Mohd Riduan Enhancement of antifouling properties using rice husk silica particles in polysulfone membrane and optimization of its operating condition |
description |
This study investigates the effects of rice husk silica (RHS) as additive in the
polysulfone membrane to enhance antifouling properties in membrane separation
process. The flat sheet PSf/RHS membrane was prepared via phase inversion
technique. The characterization and performance test were conducted on PSf
ultrafiltration membrane prepared from a different additive concentration. The
thermal stability of prepared membrane was observed by using thermogravimetric
analysis (TGA). The cross section area and particles distribution of additive were
carried out by using the scanning electron microscope (SEM) while the surface
morphology was investigated via field emission scanning electron microscope
(FESEM). The surface roughness and hydrophilicity were also determined by using
Atomic force microscopy (AFM) and contact angle measurement respectively.
Meanwhile, the performance was evaluated in term of pure water flux (PWF),
rejection and antifouling properties. The optimized of normalized flux (Jf /Jo) at
different parameter filtration condition (pH, ionic strength and tranmembranepressure)
was
carried
out
by
using
the
response
surface
methodology
(RSM).
From
the
analysis
of
SEM,
FESEM
and
AFM,
results
showed
that
the
microstructure
of
the
membrane
especially at top layer and sub layer obviously changed with the
incorporation of RHS. The results also demonstrated that the mean pore size was
decreased and hyrophilicity was increased as increased RHS particles in PSf
membrane. The performance of the membrane was analyzed by using distilled water
for permeation test and humic acid for the rejection test. The results also showed that
the hydrophilic PSf/RHS membrane has significantly improved the permeation and
rejection performance after the addition of RHS. The results showed that the addition
of 4 wt. % RHS give the highest flux at 300.50 L/m².hour (LMH). The highest
rejection was found at 3 wt. % of RHS membrane with value 98% for UV254 and
96% for TOC. The optimal value of Jf/Jo was found at 0.62 with the parameter
condition pH: 6.10, ionic strength: 0.05 mol/L and transmembrane-pressure: 2.67
bars. Optimize of RSM analysis also proved that the error of model is less than
0.05% which indicates that the model is significant. |
format |
Thesis |
qualification_name |
Master of Philosophy (M.Phil.) |
qualification_level |
Master's degree |
author |
Jamalludin, Mohd Riduan |
author_facet |
Jamalludin, Mohd Riduan |
author_sort |
Jamalludin, Mohd Riduan |
title |
Enhancement of antifouling properties using rice husk silica particles in polysulfone membrane and optimization of its operating condition |
title_short |
Enhancement of antifouling properties using rice husk silica particles in polysulfone membrane and optimization of its operating condition |
title_full |
Enhancement of antifouling properties using rice husk silica particles in polysulfone membrane and optimization of its operating condition |
title_fullStr |
Enhancement of antifouling properties using rice husk silica particles in polysulfone membrane and optimization of its operating condition |
title_full_unstemmed |
Enhancement of antifouling properties using rice husk silica particles in polysulfone membrane and optimization of its operating condition |
title_sort |
enhancement of antifouling properties using rice husk silica particles in polysulfone membrane and optimization of its operating condition |
granting_institution |
Universiti Tun Hussein Malaysia |
granting_department |
Fakulti Kejuruteraan Mekanikal dan Pembuatan |
publishDate |
2014 |
url |
http://eprints.uthm.edu.my/1559/1/24p%20MOHD%20RIDUAN%20JAMALLUDIN.pdf http://eprints.uthm.edu.my/1559/2/MOHD%20RIDUAN%20JAMALLUDIN%20COPYRIGHT%20DECLARATION.pdf http://eprints.uthm.edu.my/1559/3/MOHD%20RIDUAN%20JAMALLUDIN%20WATERMARK.pdf |
_version_ |
1747830816264683520 |