Chemical and biological reactions of solidification of peat using ordinary portland cement (OPC) and coal ashes
Construction over peat area have often posed a challenge to geotechnical engineers. After decades of study on peat stabilisation techniques, there are still no absolute formulation or guideline that have been established to handle this issue. Some researchers have proposed solidification of pe...
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| Format: | Thesis |
| Language: | English English English |
| Published: |
2021
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| Subjects: | |
| Online Access: | http://eprints.uthm.edu.my/4003/1/24p%20JUNITA%20ABD%20RAHMAN.pdf http://eprints.uthm.edu.my/4003/2/JUNITA%20ABD%20RAHMAN%20COPYRIGHT%20DECLARATION.pdf http://eprints.uthm.edu.my/4003/3/JUNITA%20ABD%20RAHMAN%20WATERMARK.pdf |
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| Summary: | Construction over peat area have often posed a challenge to geotechnical engineers.
After decades of study on peat stabilisation techniques, there are still no absolute
formulation or guideline that have been established to handle this issue. Some
researchers have proposed solidification of peat but a few researchers have also
discovered that solidified peat seemed to decrease its strength after a certain period of
time. Therefore, understanding the chemical and biological reaction behind the peat
solidification is vital to understand the limitation of this treatment technique. In this
study, all three types of peat; fabric, hemic and sapric were mixed using Mixing 1 and
Mixing 2 formulation which consisted of ordinary Portland cement, fly ash and bottom
ash at various ratio. The mixtures of peat-binder-filler were subjected to the
unconfined compressive strength (UCS) test, bacterial count test and chemical
elemental analysis by using XRF, XRD, FTIR and EDS. Two pattern of strength over
curing period were observed. Mixing 1 samples showed a steadily increase in strength
over curing period until Day 56 while Mixing 2 showed a decrease in strength pattern
at Day 28 and Day 56. Samples which increase in strength steadily have less bacterial
count and enzymatic activity with increase quantity of crystallites. Samples with lower
strength recorded increase in bacterial count and enzymatic activity with less
crystallites. Analysis using XRD showed that pargasite
(NaCa2[Mg4Al](Si6Al2)O22(OH)2) was formed in the higher strength samples while in
the lower strength samples, pargasite was predicted to be converted into monosodium
phosphate and Mg(OH)2 as bacterial consortium was re-activated. The Michaelis�Menten coefficient, Km of the bio-chemical reaction in solidified peat was calculated
as 303.60. This showed that reaction which happened during solidification work was
inefficient. The kinetics for crystallite formation with enzymatic effect is modelled as
135.42 (1/[S] + 0.44605) which means, when pargasite formed is lower, the amount
of enzyme secretes is higher. |
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