Electrokinetic-assisted phytoremediation of heavy metal in riverbank soil

Electrokinetic (EK)-assisted phytoremediation is one of the environmental remediation methods that have a big potential in enhancing the ability of plant heavy metal uptake in soils. This study was conducted to investigate the difference in heavy metal composition concentration of riverbank soil and...

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Main Author: Jamari, Suhailly
Format: Thesis
Language:English
English
English
Published: 2016
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spelling my-uthm-ep.7122021-08-30T07:20:19Z Electrokinetic-assisted phytoremediation of heavy metal in riverbank soil 2016-06 Jamari, Suhailly TD172-193.5 Environmental pollution Electrokinetic (EK)-assisted phytoremediation is one of the environmental remediation methods that have a big potential in enhancing the ability of plant heavy metal uptake in soils. This study was conducted to investigate the difference in heavy metal composition concentration of riverbank soil and the change of soil pH between pre and post phytoremediation and EK assisted phytoremediation treatment. The selected phytoremediation plant is Dieffenbachia ‘Tropic Rain”. The phytoremediation plant treatment was fertilized with organic and chemical fertilizer while the EK phytoremediation plant was induced with EK system (a pair of EK electrodes connected to a direct current (DC) power supply with a magnitude of 6 V/cm-1 electric field) for 4 hours/day. The soil and plant samples from pre and post treatments were analyzed using and X-ray Fluorescence Spectrometer (XRF), Scanning Electron Microscope / Energy Dispersive X-ray Spectroscopy (SEM/EDX) and Inductively Coupled Plasma Mass Spectrometer (ICP-MS). After 12 months of EK assisted phytoremediation treatment, the soil pH near the cathode increase 48.8% from pH 4.32 to pH 6.43 while in anode region the pH decrease 28% from pH 4.32 to pH 3.11. The element concentrations in cathode region for most elements of interest (Ni, Cu, Zn, As and Pb) were higher than anode and middle region with the highest is (47.3 ± 0.6) ppm Pb. The elemental concentration of Ni, Cu, Zn, As and Pb by EK assisted phytoremediation plants were slightly higher than the elements absorbed by the phytoremediation treated plants alone in the “chemical” and “organic” slots with the highest is (7.98 ± 0.68) ppb Zn. This showed that the EK assisted remediation treatment has increased the plant’s absorption during the phytoremediation process. 2016-06 Thesis http://eprints.uthm.edu.my/712/ http://eprints.uthm.edu.my/712/1/24p%20SUHAILLY%20JAMARI.pdf text en public http://eprints.uthm.edu.my/712/2/SUHAILLY%20JAMARI%20COPYRIGHT%20DECLARATION.pdf text en staffonly http://eprints.uthm.edu.my/712/3/SUHAILLY%20JAMARI%20WATERMARK.pdf text en validuser mphil masters Universiti Tun Hussein Onn Malaysia Faculty of Applied Sciences and Technology
institution Universiti Tun Hussein Onn Malaysia
collection UTHM Institutional Repository
language English
English
English
topic TD172-193.5 Environmental pollution
spellingShingle TD172-193.5 Environmental pollution
Jamari, Suhailly
Electrokinetic-assisted phytoremediation of heavy metal in riverbank soil
description Electrokinetic (EK)-assisted phytoremediation is one of the environmental remediation methods that have a big potential in enhancing the ability of plant heavy metal uptake in soils. This study was conducted to investigate the difference in heavy metal composition concentration of riverbank soil and the change of soil pH between pre and post phytoremediation and EK assisted phytoremediation treatment. The selected phytoremediation plant is Dieffenbachia ‘Tropic Rain”. The phytoremediation plant treatment was fertilized with organic and chemical fertilizer while the EK phytoremediation plant was induced with EK system (a pair of EK electrodes connected to a direct current (DC) power supply with a magnitude of 6 V/cm-1 electric field) for 4 hours/day. The soil and plant samples from pre and post treatments were analyzed using and X-ray Fluorescence Spectrometer (XRF), Scanning Electron Microscope / Energy Dispersive X-ray Spectroscopy (SEM/EDX) and Inductively Coupled Plasma Mass Spectrometer (ICP-MS). After 12 months of EK assisted phytoremediation treatment, the soil pH near the cathode increase 48.8% from pH 4.32 to pH 6.43 while in anode region the pH decrease 28% from pH 4.32 to pH 3.11. The element concentrations in cathode region for most elements of interest (Ni, Cu, Zn, As and Pb) were higher than anode and middle region with the highest is (47.3 ± 0.6) ppm Pb. The elemental concentration of Ni, Cu, Zn, As and Pb by EK assisted phytoremediation plants were slightly higher than the elements absorbed by the phytoremediation treated plants alone in the “chemical” and “organic” slots with the highest is (7.98 ± 0.68) ppb Zn. This showed that the EK assisted remediation treatment has increased the plant’s absorption during the phytoremediation process.
format Thesis
qualification_name Master of Philosophy (M.Phil.)
qualification_level Master's degree
author Jamari, Suhailly
author_facet Jamari, Suhailly
author_sort Jamari, Suhailly
title Electrokinetic-assisted phytoremediation of heavy metal in riverbank soil
title_short Electrokinetic-assisted phytoremediation of heavy metal in riverbank soil
title_full Electrokinetic-assisted phytoremediation of heavy metal in riverbank soil
title_fullStr Electrokinetic-assisted phytoremediation of heavy metal in riverbank soil
title_full_unstemmed Electrokinetic-assisted phytoremediation of heavy metal in riverbank soil
title_sort electrokinetic-assisted phytoremediation of heavy metal in riverbank soil
granting_institution Universiti Tun Hussein Onn Malaysia
granting_department Faculty of Applied Sciences and Technology
publishDate 2016
url http://eprints.uthm.edu.my/712/1/24p%20SUHAILLY%20JAMARI.pdf
http://eprints.uthm.edu.my/712/2/SUHAILLY%20JAMARI%20COPYRIGHT%20DECLARATION.pdf
http://eprints.uthm.edu.my/712/3/SUHAILLY%20JAMARI%20WATERMARK.pdf
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