Feasibility of waste-derived hydroxyapatite mixed with ultra highm olecular weight polyethylene composites for fused deposition modeling process

In this study, feasibility of waste-derived hydroxyapatite (HAp) reinforced UHMWPE composites for Fused Deposition Modeling (FDM) process was investigated. Compared to the commercial HAp, derived from natural resources such as corals, fish bone and eggshells have been converted into HAp and show the...

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Main Author:	Md Ansari, Mohamad Helmi
Format:	Thesis
Language:	English English English
Published:	2018
Subjects:	QE Geology QE351-399.2 Mineralogy
Online Access:	http://eprints.uthm.edu.my/7546/1/24p%20MOHAMAD%20HELMI%20MD%20ANSARI.pdf http://eprints.uthm.edu.my/7546/2/MOHAMAD%20HELMI%20MD%20ANSARI%20COPYRIGHT%20DECLARATION.pdf http://eprints.uthm.edu.my/7546/3/MOHAMAD%20HELMI%20MD%20ANSARI%20WATERMARK.pdf
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spelling	my-uthm-ep.75462022-08-21T01:44:02Z Feasibility of waste-derived hydroxyapatite mixed with ultra highm olecular weight polyethylene composites for fused deposition modeling process 2018-09 Md Ansari, Mohamad Helmi QE Geology QE351-399.2 Mineralogy In this study, feasibility of waste-derived hydroxyapatite (HAp) reinforced UHMWPE composites for Fused Deposition Modeling (FDM) process was investigated. Compared to the commercial HAp, derived from natural resources such as corals, fish bone and eggshells have been converted into HAp and show the similarity with the commercial HAp. Ca/P ratio was so important to human body because Ca influence growth of human bones and P play a role in immune system activation. This research has used waste eggshell has been used to synthesize HAp by using hydrothermal synthesis. The Ca/P ratio was investigated by using SEM/EDS and XRD test. By using these test, it revealed Ca/P ratio of waste-derived HAp has shown 1.69 approximately with the standard Ca/P ratio (1.67). HAp/UHMWPE composites formulation samples were prepared by mixed between HAp and UHMWPE using Brabender Mixer. HAp/UHMWPE composite formulation samples were characterized by their weight percentage. The feasibility of each HAp/UHMWPE composite samples has been studied by their morphology, thermal and rheology properties by using SEM/EDS, TOA/DSC and Rheology test. Formulation sample U50H50 with 50 wt.% of HAp has shown the homogenous mixture, 1.69 Ca/P ratio, lowest melting point and good pseudo-plastic behavior compared to other formulation samples. Therefore, this formulation samples has been used in single screw extruder to fabricate diameter size of I. 75±0.05 mm filament wire for FDM process. DOE has been developed by using Taguchi method with the parameter controlled were die temperature and screw frequency. The optimum parameter setting to produce the diameter of 1.75±0.05 mm filament wire was successfully found at screw frequency of 2.5 Hz and die temperature of 190 °C. The characteristic of the FDM process shows the samples with optimum dimensional accuracy and relative density was found at 245 °C of temperature nozzle and 130 °C of temperature platform. This result shown Hap/UHMWPE composite has potential to become material filament wire feedstock for FDM process. 2018-09 Thesis http://eprints.uthm.edu.my/7546/ http://eprints.uthm.edu.my/7546/1/24p%20MOHAMAD%20HELMI%20MD%20ANSARI.pdf text en public http://eprints.uthm.edu.my/7546/2/MOHAMAD%20HELMI%20MD%20ANSARI%20COPYRIGHT%20DECLARATION.pdf text en staffonly http://eprints.uthm.edu.my/7546/3/MOHAMAD%20HELMI%20MD%20ANSARI%20WATERMARK.pdf text en validuser mphil masters Universiti Tun Hussein Onn Malaysia Fakulti Kejuruteraan Mekanikal dan Pembuatan
institution	Universiti Tun Hussein Onn Malaysia
collection	UTHM Institutional Repository
language	English English English
topic	QE Geology QE351-399.2 Mineralogy
spellingShingle	QE Geology QE351-399.2 Mineralogy Md Ansari, Mohamad Helmi Feasibility of waste-derived hydroxyapatite mixed with ultra highm olecular weight polyethylene composites for fused deposition modeling process
description	In this study, feasibility of waste-derived hydroxyapatite (HAp) reinforced UHMWPE composites for Fused Deposition Modeling (FDM) process was investigated. Compared to the commercial HAp, derived from natural resources such as corals, fish bone and eggshells have been converted into HAp and show the similarity with the commercial HAp. Ca/P ratio was so important to human body because Ca influence growth of human bones and P play a role in immune system activation. This research has used waste eggshell has been used to synthesize HAp by using hydrothermal synthesis. The Ca/P ratio was investigated by using SEM/EDS and XRD test. By using these test, it revealed Ca/P ratio of waste-derived HAp has shown 1.69 approximately with the standard Ca/P ratio (1.67). HAp/UHMWPE composites formulation samples were prepared by mixed between HAp and UHMWPE using Brabender Mixer. HAp/UHMWPE composite formulation samples were characterized by their weight percentage. The feasibility of each HAp/UHMWPE composite samples has been studied by their morphology, thermal and rheology properties by using SEM/EDS, TOA/DSC and Rheology test. Formulation sample U50H50 with 50 wt.% of HAp has shown the homogenous mixture, 1.69 Ca/P ratio, lowest melting point and good pseudo-plastic behavior compared to other formulation samples. Therefore, this formulation samples has been used in single screw extruder to fabricate diameter size of I. 75±0.05 mm filament wire for FDM process. DOE has been developed by using Taguchi method with the parameter controlled were die temperature and screw frequency. The optimum parameter setting to produce the diameter of 1.75±0.05 mm filament wire was successfully found at screw frequency of 2.5 Hz and die temperature of 190 °C. The characteristic of the FDM process shows the samples with optimum dimensional accuracy and relative density was found at 245 °C of temperature nozzle and 130 °C of temperature platform. This result shown Hap/UHMWPE composite has potential to become material filament wire feedstock for FDM process.
format	Thesis
qualification_name	Master of Philosophy (M.Phil.)
qualification_level	Master's degree
author	Md Ansari, Mohamad Helmi
author_facet	Md Ansari, Mohamad Helmi
author_sort	Md Ansari, Mohamad Helmi
title	Feasibility of waste-derived hydroxyapatite mixed with ultra highm olecular weight polyethylene composites for fused deposition modeling process
title_short	Feasibility of waste-derived hydroxyapatite mixed with ultra highm olecular weight polyethylene composites for fused deposition modeling process
title_full	Feasibility of waste-derived hydroxyapatite mixed with ultra highm olecular weight polyethylene composites for fused deposition modeling process
title_fullStr	Feasibility of waste-derived hydroxyapatite mixed with ultra highm olecular weight polyethylene composites for fused deposition modeling process
title_full_unstemmed	Feasibility of waste-derived hydroxyapatite mixed with ultra highm olecular weight polyethylene composites for fused deposition modeling process
title_sort	feasibility of waste-derived hydroxyapatite mixed with ultra highm olecular weight polyethylene composites for fused deposition modeling process
granting_institution	Universiti Tun Hussein Onn Malaysia
granting_department	Fakulti Kejuruteraan Mekanikal dan Pembuatan
publishDate	2018
url	http://eprints.uthm.edu.my/7546/1/24p%20MOHAMAD%20HELMI%20MD%20ANSARI.pdf http://eprints.uthm.edu.my/7546/2/MOHAMAD%20HELMI%20MD%20ANSARI%20COPYRIGHT%20DECLARATION.pdf http://eprints.uthm.edu.my/7546/3/MOHAMAD%20HELMI%20MD%20ANSARI%20WATERMARK.pdf
_version_	1747831165863067648

Feasibility of waste-derived hydroxyapatite mixed with ultra highm olecular weight polyethylene composites for fused deposition modeling process

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