Electrical characterisation of multi-walled carbon nanotube/polydimethylsiloxane using improved facile dispersion technique

The growth of polymer composite in technological advancement has contributed to the development of electrocardiogram (ECG) electrode, which gives better wearable conformality on human skin. This gives a promising alternative to Multi-Walled Carbon Nanotube (MWCNT) and polydimethylsiloxane (PDMS) due...

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Main Author: Mohd. Zambri, Izzaty
Format: Thesis
Language:English
Published: 2021
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Online Access:http://eprints.utm.my/id/eprint/102289/1/IzzatyMohdZambriMSKE2021.pdf.pdf
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spelling my-utm-ep.1022892023-08-17T00:34:32Z Electrical characterisation of multi-walled carbon nanotube/polydimethylsiloxane using improved facile dispersion technique 2021 Mohd. Zambri, Izzaty TK Electrical engineering. Electronics Nuclear engineering The growth of polymer composite in technological advancement has contributed to the development of electrocardiogram (ECG) electrode, which gives better wearable conformality on human skin. This gives a promising alternative to Multi-Walled Carbon Nanotube (MWCNT) and polydimethylsiloxane (PDMS) due to its low cost, ease of manufacturing and flexibility. However, with the high aspect ratio and strong Van der Waals interaction forces, MWCNT easily agglomerates, and bundling to each other. An effective dispersion technique of MWCNT/PDMS composite is essential to enhance the electrical conductivity by controlling MWCNT content and maintaining electrode flexibility. Thus, this study disperses the MWCNT/PDMS composite using a solution mixing method: sonication process and mechanical stirring. The MWCNT is dispersed using toluene solvent to achieve uniform dispersion, where the MWCNT content varies from 2 wt% to 10 wt% in PDMS matrix. As a result, the MWCNT/PDMS composite conductivity is in the range of 0.30 × 10-9 S/cm to 6.14 × 10-6 S/cm. At 4 wt%, the MWCNT/PDMS composite reached the percolation threshold region. The fabricated polymer composite was further characterised in Raman spectroscopy and the measurement shows vibration peaks in the D-band at 1349 cm-1 and G-band at 1585 cm-1. This proves the dispersion of MWCNT in PDMS. In addition, the intensity of the D-band and G-band, ID/IG decreases when the MWCNT/PDMS concentration increases, indicating less defect of MWCNT during the sonication process. These findings show that the MWCNT/PDMS has the potential as an excellent polymer composite electrode. 2021 Thesis http://eprints.utm.my/id/eprint/102289/ http://eprints.utm.my/id/eprint/102289/1/IzzatyMohdZambriMSKE2021.pdf.pdf application/pdf en public http://dms.library.utm.my:8080/vital/access/manager/Repository/vital:149297 masters Universiti Teknologi Malaysia Faculty of Engineering - School of Electrical Engineering
institution Universiti Teknologi Malaysia
collection UTM Institutional Repository
language English
topic TK Electrical engineering
Electronics Nuclear engineering
spellingShingle TK Electrical engineering
Electronics Nuclear engineering
Mohd. Zambri, Izzaty
Electrical characterisation of multi-walled carbon nanotube/polydimethylsiloxane using improved facile dispersion technique
description The growth of polymer composite in technological advancement has contributed to the development of electrocardiogram (ECG) electrode, which gives better wearable conformality on human skin. This gives a promising alternative to Multi-Walled Carbon Nanotube (MWCNT) and polydimethylsiloxane (PDMS) due to its low cost, ease of manufacturing and flexibility. However, with the high aspect ratio and strong Van der Waals interaction forces, MWCNT easily agglomerates, and bundling to each other. An effective dispersion technique of MWCNT/PDMS composite is essential to enhance the electrical conductivity by controlling MWCNT content and maintaining electrode flexibility. Thus, this study disperses the MWCNT/PDMS composite using a solution mixing method: sonication process and mechanical stirring. The MWCNT is dispersed using toluene solvent to achieve uniform dispersion, where the MWCNT content varies from 2 wt% to 10 wt% in PDMS matrix. As a result, the MWCNT/PDMS composite conductivity is in the range of 0.30 × 10-9 S/cm to 6.14 × 10-6 S/cm. At 4 wt%, the MWCNT/PDMS composite reached the percolation threshold region. The fabricated polymer composite was further characterised in Raman spectroscopy and the measurement shows vibration peaks in the D-band at 1349 cm-1 and G-band at 1585 cm-1. This proves the dispersion of MWCNT in PDMS. In addition, the intensity of the D-band and G-band, ID/IG decreases when the MWCNT/PDMS concentration increases, indicating less defect of MWCNT during the sonication process. These findings show that the MWCNT/PDMS has the potential as an excellent polymer composite electrode.
format Thesis
qualification_level Master's degree
author Mohd. Zambri, Izzaty
author_facet Mohd. Zambri, Izzaty
author_sort Mohd. Zambri, Izzaty
title Electrical characterisation of multi-walled carbon nanotube/polydimethylsiloxane using improved facile dispersion technique
title_short Electrical characterisation of multi-walled carbon nanotube/polydimethylsiloxane using improved facile dispersion technique
title_full Electrical characterisation of multi-walled carbon nanotube/polydimethylsiloxane using improved facile dispersion technique
title_fullStr Electrical characterisation of multi-walled carbon nanotube/polydimethylsiloxane using improved facile dispersion technique
title_full_unstemmed Electrical characterisation of multi-walled carbon nanotube/polydimethylsiloxane using improved facile dispersion technique
title_sort electrical characterisation of multi-walled carbon nanotube/polydimethylsiloxane using improved facile dispersion technique
granting_institution Universiti Teknologi Malaysia
granting_department Faculty of Engineering - School of Electrical Engineering
publishDate 2021
url http://eprints.utm.my/id/eprint/102289/1/IzzatyMohdZambriMSKE2021.pdf.pdf
_version_ 1776100888373362688