Simulation and optimization of butane autothermal reformer for fuel cell applications

Hydrogen (H2) production has gaining popularity among researchers to aim a better future environment. H2 is very excellent candidate to replace the existing fuel. Its high flammability and energy produced alongside no side product generated make it even more popular. The objective of the study is to...

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Main Author: Abdullah, Mohd. Shahir
Format: Thesis
Language:English
Published: 2006
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Online Access:http://eprints.utm.my/id/eprint/1471/1/MohamadShahirAbdullahFKKSA2006.pdf
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id my-utm-ep.1471
record_format uketd_dc
institution Universiti Teknologi Malaysia
collection UTM Institutional Repository
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
Abdullah, Mohd. Shahir
Simulation and optimization of butane autothermal reformer for fuel cell applications
description Hydrogen (H2) production has gaining popularity among researchers to aim a better future environment. H2 is very excellent candidate to replace the existing fuel. Its high flammability and energy produced alongside no side product generated make it even more popular. The objective of the study is to develop a general steady-state simulation of H2 production plant for fuel cell application using butane as the feedstock. The scopes of the study include stoichiometry mathematical calculations, base case steady-state simulation, base case simulation validation, a design of heat integration, carbon monoxide (CO) clean-up processes which contains water gas shift (WGS) and preferential oxidation (PrOx) reactors and plant wide optimization. The simulation has been run in Aspen HYSYS 2004.1 in steady-state mode in which optimization was done to generate more H2 as well as CO reduction. The butane fuel processor was optimized at O/C ratio of 2.18 and S/C ratio of 4.6 to produce 39.2% of H2 and has achieved 78.1% efficiency. While CO clean-up units was capable to reduce the CO concentration down to 10 ppm.
format Thesis
qualification_level other
author Abdullah, Mohd. Shahir
author_facet Abdullah, Mohd. Shahir
author_sort Abdullah, Mohd. Shahir
title Simulation and optimization of butane autothermal reformer for fuel cell applications
title_short Simulation and optimization of butane autothermal reformer for fuel cell applications
title_full Simulation and optimization of butane autothermal reformer for fuel cell applications
title_fullStr Simulation and optimization of butane autothermal reformer for fuel cell applications
title_full_unstemmed Simulation and optimization of butane autothermal reformer for fuel cell applications
title_sort simulation and optimization of butane autothermal reformer for fuel cell applications
granting_institution Universiti Teknologi Malaysia, Chemical Engineering Department
granting_department Chemical Engineering Department
publishDate 2006
url http://eprints.utm.my/id/eprint/1471/1/MohamadShahirAbdullahFKKSA2006.pdf
_version_ 1747814377919086592
spelling my-utm-ep.14712018-02-20T05:09:43Z Simulation and optimization of butane autothermal reformer for fuel cell applications 2006-11 Abdullah, Mohd. Shahir TP Chemical technology Hydrogen (H2) production has gaining popularity among researchers to aim a better future environment. H2 is very excellent candidate to replace the existing fuel. Its high flammability and energy produced alongside no side product generated make it even more popular. The objective of the study is to develop a general steady-state simulation of H2 production plant for fuel cell application using butane as the feedstock. The scopes of the study include stoichiometry mathematical calculations, base case steady-state simulation, base case simulation validation, a design of heat integration, carbon monoxide (CO) clean-up processes which contains water gas shift (WGS) and preferential oxidation (PrOx) reactors and plant wide optimization. The simulation has been run in Aspen HYSYS 2004.1 in steady-state mode in which optimization was done to generate more H2 as well as CO reduction. The butane fuel processor was optimized at O/C ratio of 2.18 and S/C ratio of 4.6 to produce 39.2% of H2 and has achieved 78.1% efficiency. While CO clean-up units was capable to reduce the CO concentration down to 10 ppm. 2006-11 Thesis http://eprints.utm.my/id/eprint/1471/ http://eprints.utm.my/id/eprint/1471/1/MohamadShahirAbdullahFKKSA2006.pdf application/pdf en public other Universiti Teknologi Malaysia, Chemical Engineering Department Chemical Engineering Department Aartun, I., Gjervan, T., Venvik, H., Görke, O., Pfeifer, P., Fathi, M., Holmena, A. and Schubert, K. (2004). “Catalytic Conversion of Propane to Hydrogen in Microstructured Reactors.� Chemical Engineering Journal. 101. 93–99. Ahmet, K., Gamman, J. and Foger, K. (2002). “Demonstration of LPG-fueled Solid Oxide Fuel Cell Systems.� Solid State Ionics. 152-153. 485-492. Aspen Tech. Aspen HYSYS 2004.1 Documentation. Avci, A. K., Trimm, D. L. Aksoylu, A. E. and Onsan, Z. I. (2004). “Hydrogen Production by Steam Reforming of N-butane over Supported Ni and Pt-Ni Catalysts.� Applied Catalysis A: General. 258. 235-240. Basile, A., Gallucci, F. and Paturzo, L. (2005). “Hydrogen Production from Methanol by Oxidative Steam Reforming Carried out in a Membrane Reactor.� Catalysis Today. 104. 251-259. Caglayan, B. S., Avcı, A. K., Onsan, Z. I. and Aksoylu, A. E. (2005). “Production of Hydrogen over Bimetallic Pt–Ni/d-Al2O3 I. Indirect Partial Oxidation of Propane.� Applied Catalysis A: General. 280. 181–188. Chin, S. Y., Chin, Y. H. and Amiridis, M. D. (2006). “Hydrogen Production via the Catalytic Cracking of Ethane over Ni/SiO2 Catalysts.� Applied Catalysis A: General. 300. 8-13. Choudhary, T. V., Sivadinarayana, C., Chusuei, C. C., Klinghoffer, A. and Goodman, D. W. (2001). “Hydrogen Production via Catalytic Decomposition of Methane.� Journal of Catalysis. 199. 9-18. Cipitı, F., Recupero, V. Pino, L., Vita, A. and Lagan, M. (2006). “Experimental Analysis of a 2kWe LPG-based Fuel Processor for Polymer Electrolyte Fuel Cells.� Journal of Power Sources. 157. 914-920. Comas, J., Laborde, M. and Amadeo, N. (2004). “Thermodynamic Analysis of Hydrogen Production from Ethanol using CaO as a CO2 Sorbent.� Journal of Power Sources. 138. 61-67. Darwish, N. A., Hilal, N., Versteeg, G. and Heesink, B. (2004). “Feasibility of the Direct Generation of Hydrogen for Fuel-cell-powered Vehicles On-board Steam Reforming of Naphtha.� Fuel. 83. 409-417. Dong, W. S., Roh, H. S., Liu, Z. W., Jun, K. W. and Park, S. E. (2001). “Hydrogen Production from Methane Reforming Reactions over Ni/MgO Catalyst.� Bull. Korean Chem. Soc. 22, No. 12. 1323-1327. Ersoz, A., Olgun, H., Ozdogan, S., Gungor, C., Akgun, F. and Tiris, M. (2003). “Autothermal Reforming as a Hydrocarbon Fuel Processing Option for PEM Fuel Cell.� Power Sources. 118. 384-392. Fraser, S.D., Monsberger, M. and Hacker, V. (2006). “A Thermodynamic Analysis of the Reformer Sponge Iron Cycle.� Journal of Power Sources. 161. 420-431. Galvita, V. and Sunmacher K. (2005) “Hydrogen Production from Methane by Steam Reforming in a Periodically Operated Two-layer Catalytic Reactor.� Applied Catalysis A: General. 289. 121-127. Goula, M. A., Kontou, S. K. and Tsiakaras, P. E. (2004). “Hydrogen Production by Ethanol Steam Reforming over a Commercial Pd/ γ-Al2O3 Catalyst.� Applied Catalysis B: Environmental. 49. 135-144. Junge, H. and Beller, M. (2005). “Ruthenium-catalyzed Generation of Hydrogen from Iso-propanol.� Tetrahedron Letters. 46. 1031-1034. Karagiannakis, G., Kokkofitis, C., Zisekas, S. and Stoukides, M. (2005). “Catalytic and Electrocatalytic Production of H2 from Propane Decomposition over Pt and Pd in a Proton-conducting Membrane-reactor.� Catalysis Today. 104. 219-224. Kothari, R., Buddhi, D. and Sawhney, R. L. (2004). “Sources and Technology for Hydrogen Production: a Review.� Int. J. Global Energy. 21, Nos. 1/2. 154-178. Lattner, J. R. and Harold, M. P. (2004). “Comparison of Conventional and Membrane Reactor Fuel Processors for Hydrocarbon-based PEM Fuel Cell Systems.� International Journal of Hydrogen Energy. 29. 393-417. Lin, A. T., Chen, Y. H., Yu, C. C., Liu, Y. C. and Lee, C. H. (2006). “Dynamic Modeling and Control Structure Design of an Experimental Fuel Processor.� International Journal of Hydrogen Energy. 31. 413-426. Liu, S., Takahashi, K., Fuchigami, K. and Uematsu, K. (2006). “Hydrogen Production by Oxidative Methanol Reforming on Pd/ZnO: Catalyst Deactivation.� Applied Catalysis A: General. 299. 58-65. Mattos, L. V. and Noronha, F.B., (2005). “Hydrogen Production for Fuel Cell Applications by Ethanol Partial Oxidation on Pt/CeO2 Catalysts: The Effect of the Reaction Conditions and Reaction Mechanism.� Journal of Catalysis. 233. 453-463. Minutillo, M. (2005). “On-board Fuel Processor Modelling for Hydrogen-enriched Gasoline Fuelled Engine.� International Journal of Hydrogen Energy. 30. 1483-1490. Mizuno, T., Matsumura, Y., Nakajima, T. and Mishima, S. (2003). “Effect of Support on Catalytic Properties of Rh Catalysts for Steam Reforming of 2-Propanol.� International Journal of Hydrogen Energy. 28. 1393-1399. Nakagawa, K., Mikka, N. G. and Ando, T. (2005). “Hydrogen Production from Methane for Fuel Cell Using Oxidized Diamond-supported Catalysts.� International Journal of Hydrogen Energy. 30. 201-207. Otsuka, K., Shigeta, Y. and Takenaka, S. (2002). “Production of Hydrogen from Gasoline Range Alkanes with Reduced CO2 Emission.� International Journal of Hydrogen Energy. 27. 11-18. Recupero, V., Pino, L., Vita, A., Cipiti, F., Cordaro, M. and Lagane, M. (2005). “Development of a LPG Fuel Cell Processor for PEFC Systems: Laboratory Scale Evaluation of Autothermal Reforming and Preferential Oxidation Subunits.� International Journal of Hydrogen Energy. 30. 963-971. Soo, Y. C., Chin, Y. H. and Amiridis, M. D. (2006). “Hydrogen Production via the Catalytic Cracking of Ethane over Ni/SiO2.� Applied Catalysis A: General. 300. 8-13. Suzuki, T., Iwanami, H. and Yoshinari, T. (2000). “Steam Reforming of Kerosene on Ru/Al2O3 Catalyst to Yield Hydrogen.� International Journal of Hydrogen Energy. 25. 119-126. Steinberg, M. (2006). “Conversion of Fossil and Biomass Fuel to Electric Power and transportation Fuel by high Efficiency Integrated Plasma Fuel Cell (IPFC) Energy Cycle.� International Journal of Hydrogen Energy. 31. 405-411. Wang, Y. N. and Rodrigues, A. E. (2005) “Hydrogen Production from Steam Methane Reforming Coupled with in situ CO2 Capture: Conceptual Parametric Study.� Fuel. 84. 1778-1789. Xu, Y., Kameoka, S., Kishida, K. Demura, M., Tsai, A. and Hirano, T. (2005). “Catalytic Properties of Alkali-leached Ni3Al for Hydrogen Production from Methanol.� Intermetallics. 13. 151-155. Ye, Y., Liisa, R. S., Munder, B. and Sundmacher, K. (2005). “Partial Oxidation of N-butane in a Solid Electrolyte Membrane Reactor: Periodic and Steady-state Operations.� Applied Catalysis A: General. 285. 86-95.