Physical and thermal properties of polypropylene/rice straw biocomposite foam

Polymer foam biocomposites based on polypropylene/rice straw (PP/RS) were successfully prepared by using an extrusion foaming process. The compounding of PP and RS was performed in a twin-screw extruder which was blended with crosslinker; dicumyl peroxide (DCP), blowing agent; azodicarbonamide (AZ)...

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Main Author: Tugiman, Nazuha
Format: Thesis
Language:English
Published: 2013
Subjects:
Online Access:http://eprints.utm.my/id/eprint/39758/5/NazuhaTugimanMFKK2013.pdf
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spelling my-utm-ep.397582017-07-06T04:28:06Z Physical and thermal properties of polypropylene/rice straw biocomposite foam 2013-07 Tugiman, Nazuha TA Engineering (General). Civil engineering (General) Polymer foam biocomposites based on polypropylene/rice straw (PP/RS) were successfully prepared by using an extrusion foaming process. The compounding of PP and RS was performed in a twin-screw extruder which was blended with crosslinker; dicumyl peroxide (DCP), blowing agent; azodicarbonamide (AZ) and different compatibilizers; polypropylene maleic anhydride (PPMAH) and ULTRAPLASTTM TP10. Compatibilizers were utilised to improve poor interfacial interaction between hydrophilic rice straw and hydrophobic matrix polypropylene. The foam biocomposite was extruded at temperatures of 180, 190, 190 and 200 °C respectively, which set from the feeder until the die zone. Each sample has five different series of formulations. The density test, water absorption test and gel content test were conducted to study the physical properties of PP/RS biocomposite foam. The thermal properties were also investigated by using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). Meanwhile, the morphologies of the biocomposite foams were observed through scanning electron microscopy (SEM). The incorporation of PPMAH or TP10 improved the compatibility and processability of PP/RS biocomposite foam. This formulation has produced a good cell structure, lower density of biocomposite, improved the water uptake resistance and exhibited the best crosslinking density. 2013-07 Thesis http://eprints.utm.my/id/eprint/39758/ http://eprints.utm.my/id/eprint/39758/5/NazuhaTugimanMFKK2013.pdf application/pdf en public masters Universiti Teknologi Malaysia, Faculty of Chemical Engineering Faculty of Chemical Engineering
institution Universiti Teknologi Malaysia
collection UTM Institutional Repository
language English
topic TA Engineering (General)
Civil engineering (General)
spellingShingle TA Engineering (General)
Civil engineering (General)
Tugiman, Nazuha
Physical and thermal properties of polypropylene/rice straw biocomposite foam
description Polymer foam biocomposites based on polypropylene/rice straw (PP/RS) were successfully prepared by using an extrusion foaming process. The compounding of PP and RS was performed in a twin-screw extruder which was blended with crosslinker; dicumyl peroxide (DCP), blowing agent; azodicarbonamide (AZ) and different compatibilizers; polypropylene maleic anhydride (PPMAH) and ULTRAPLASTTM TP10. Compatibilizers were utilised to improve poor interfacial interaction between hydrophilic rice straw and hydrophobic matrix polypropylene. The foam biocomposite was extruded at temperatures of 180, 190, 190 and 200 °C respectively, which set from the feeder until the die zone. Each sample has five different series of formulations. The density test, water absorption test and gel content test were conducted to study the physical properties of PP/RS biocomposite foam. The thermal properties were also investigated by using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). Meanwhile, the morphologies of the biocomposite foams were observed through scanning electron microscopy (SEM). The incorporation of PPMAH or TP10 improved the compatibility and processability of PP/RS biocomposite foam. This formulation has produced a good cell structure, lower density of biocomposite, improved the water uptake resistance and exhibited the best crosslinking density.
format Thesis
qualification_level Master's degree
author Tugiman, Nazuha
author_facet Tugiman, Nazuha
author_sort Tugiman, Nazuha
title Physical and thermal properties of polypropylene/rice straw biocomposite foam
title_short Physical and thermal properties of polypropylene/rice straw biocomposite foam
title_full Physical and thermal properties of polypropylene/rice straw biocomposite foam
title_fullStr Physical and thermal properties of polypropylene/rice straw biocomposite foam
title_full_unstemmed Physical and thermal properties of polypropylene/rice straw biocomposite foam
title_sort physical and thermal properties of polypropylene/rice straw biocomposite foam
granting_institution Universiti Teknologi Malaysia, Faculty of Chemical Engineering
granting_department Faculty of Chemical Engineering
publishDate 2013
url http://eprints.utm.my/id/eprint/39758/5/NazuhaTugimanMFKK2013.pdf
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