Nickel removal from electroless nickel plating wastewater using chitosan-membrane filtration

Nickel solution used in the plating process results in the contamination of the wastewater stream which is very hazardous and toxic to human, animal and the environment. Electroless nickel wastewater must be treated before being dumped into water bodies. Membrane filtration and adsorption have been...

Full description

Saved in:
Bibliographic Details
Main Author: Juiani, Siti Fairuz
Format: Thesis
Published: 2013
Subjects:
Tags: Add Tag
No Tags, Be the first to tag this record!
id my-utm-ep.42175
record_format uketd_dc
spelling my-utm-ep.421752020-08-10T08:20:09Z Nickel removal from electroless nickel plating wastewater using chitosan-membrane filtration 2013 Juiani, Siti Fairuz TP Chemical technology Nickel solution used in the plating process results in the contamination of the wastewater stream which is very hazardous and toxic to human, animal and the environment. Electroless nickel wastewater must be treated before being dumped into water bodies. Membrane filtration and adsorption have been widely applied in wastewater containing heavy metals. Adsorption process is the main treatment method and membrane filtration acted as a post treatment. Since adsorption is renowned as a promising technique in heavy metal removal, chitosan solution as an adsorbent showed higher advantages compared to chitosan flakes. The parameters studied were pH, adsorbent dosage and contact time and their optimum conditions were found to be 5.75, 2.11g/L, and 81 minute respectively obtained by using Response Surface Methodology (RSM) from STATISTICA v8.0. After treated by adsorption, the wastewater was filtered by Whatman filter paper and followed by membrane filtration while using the submerged hollow fiber system. The critical flux was determined by critical flux step and the operational flux used was flux four. The results show that, nickel removal was 95.18% when using adsorption. By integrating the two processes of adsorption-membrane filtration, nickel removal obtained was 98.27% and the adsorption process helped to reduce membrane fouling. For the isotherm and kinetics study in adsorption process, the experimental data were found to fit the Freundlich isotherm and Pseudo-second order kinetics. In conclusion, adsorption-membrane filtration process was found to be an effective treatment option for wastewater containing nickel. 2013 Thesis http://eprints.utm.my/id/eprint/42175/ http://dms.library.utm.my:8080/vital/access/manager/Repository/vital:75236 masters Universiti Teknologi Malaysia, Faculty of Chemical Engineering Faculty of Chemical Engineering
institution Universiti Teknologi Malaysia
collection UTM Institutional Repository
topic TP Chemical technology
spellingShingle TP Chemical technology
Juiani, Siti Fairuz
Nickel removal from electroless nickel plating wastewater using chitosan-membrane filtration
description Nickel solution used in the plating process results in the contamination of the wastewater stream which is very hazardous and toxic to human, animal and the environment. Electroless nickel wastewater must be treated before being dumped into water bodies. Membrane filtration and adsorption have been widely applied in wastewater containing heavy metals. Adsorption process is the main treatment method and membrane filtration acted as a post treatment. Since adsorption is renowned as a promising technique in heavy metal removal, chitosan solution as an adsorbent showed higher advantages compared to chitosan flakes. The parameters studied were pH, adsorbent dosage and contact time and their optimum conditions were found to be 5.75, 2.11g/L, and 81 minute respectively obtained by using Response Surface Methodology (RSM) from STATISTICA v8.0. After treated by adsorption, the wastewater was filtered by Whatman filter paper and followed by membrane filtration while using the submerged hollow fiber system. The critical flux was determined by critical flux step and the operational flux used was flux four. The results show that, nickel removal was 95.18% when using adsorption. By integrating the two processes of adsorption-membrane filtration, nickel removal obtained was 98.27% and the adsorption process helped to reduce membrane fouling. For the isotherm and kinetics study in adsorption process, the experimental data were found to fit the Freundlich isotherm and Pseudo-second order kinetics. In conclusion, adsorption-membrane filtration process was found to be an effective treatment option for wastewater containing nickel.
format Thesis
qualification_level Master's degree
author Juiani, Siti Fairuz
author_facet Juiani, Siti Fairuz
author_sort Juiani, Siti Fairuz
title Nickel removal from electroless nickel plating wastewater using chitosan-membrane filtration
title_short Nickel removal from electroless nickel plating wastewater using chitosan-membrane filtration
title_full Nickel removal from electroless nickel plating wastewater using chitosan-membrane filtration
title_fullStr Nickel removal from electroless nickel plating wastewater using chitosan-membrane filtration
title_full_unstemmed Nickel removal from electroless nickel plating wastewater using chitosan-membrane filtration
title_sort nickel removal from electroless nickel plating wastewater using chitosan-membrane filtration
granting_institution Universiti Teknologi Malaysia, Faculty of Chemical Engineering
granting_department Faculty of Chemical Engineering
publishDate 2013
_version_ 1747816708029022208