Influence of ultrasonic vibration on TiN coated biomedical TI-13Zr-13Nb alloy

Biomedical grade of titanium alloys are prone to undergo degradation in body fluid environment. Surface coating such as Physical Vapor Deposition (PVD) can serve as one of the alternatives to minimize this issue. Past reports highlighted that coated PVD layer consists of pores, pin holes and columna...

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Main Author: Abdullah, Arman Shah
Format: Thesis
Language:English
Published: 2015
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Online Access:http://eprints.utm.my/id/eprint/54826/1/ArmanShahAbdullahPFKM2015.pdf
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spelling my-utm-ep.548262020-11-08T06:58:03Z Influence of ultrasonic vibration on TiN coated biomedical TI-13Zr-13Nb alloy 2015-10 Abdullah, Arman Shah TJ Mechanical engineering and machinery Biomedical grade of titanium alloys are prone to undergo degradation in body fluid environment. Surface coating such as Physical Vapor Deposition (PVD) can serve as one of the alternatives to minimize this issue. Past reports highlighted that coated PVD layer consists of pores, pin holes and columnar growth which act as channels for the aggressive medium to attack the substrate. Duplex and multilayer coatings seem able to address this issue at certain extent but at the expense of manufacturing time and cost. In the present work, the effect of ultrasonic vibration parameters on PVD-Titanium Nitride (TiN) coated Ti-13Zr-13Nb biomedical alloy was studied. Disk type samples were prepared and coated with TiN at various conditions: bias voltage (-125V), substrate temperature (100 to 300 ºC) and nitrogen gas flow rate (100 to 300 sccm). Ultrasonic vibration was then subsequently applied on extreme high and low conditions of TiN coated samples at two different frequencies (8 kHz, 16 kHz) and three set of exposure times (5 min, 8 min, 11 min). Encouraging results of PVD coating are observed on the samples coated at higher polarity of nitrogen gas flow rate (300 sccm) and substrate temperature (300 ºC) in terms of providing better surface morphology and roughness, coating thickness and adhesion strength. All TiN coated samples treated with ultrasonic vibration exhibit higher corrosion resistance than the untreated ones. Microstructure analysis under (Field Emission Scanning Electron Microscopy (FESEM) confirms that the higher ultrasonic frequency (16 kHz) and the longer exposure time (11 minutes) produce the most compact coating. It is believed that hammering effect from ultrasonic vibration reduces the micro channels’ size in the coating and thus decelerates the corrosion attack. Nano indentation test conducted on the ultrasonic treated samples provides a higher Hardness/Elasticity (H/E) ratio than untreated ones. This suggests that the ultrasonic vibration treated samples could also have a lower wear rate. 2015-10 Thesis http://eprints.utm.my/id/eprint/54826/ http://eprints.utm.my/id/eprint/54826/1/ArmanShahAbdullahPFKM2015.pdf application/pdf en public http://dms.library.utm.my:8080/vital/access/manager/Repository/vital:96008 phd doctoral Universiti Teknologi Malaysia, Faculty of Mechanical Engineering Faculty of Mechanical Engineering
institution Universiti Teknologi Malaysia
collection UTM Institutional Repository
language English
topic TJ Mechanical engineering and machinery
spellingShingle TJ Mechanical engineering and machinery
Abdullah, Arman Shah
Influence of ultrasonic vibration on TiN coated biomedical TI-13Zr-13Nb alloy
description Biomedical grade of titanium alloys are prone to undergo degradation in body fluid environment. Surface coating such as Physical Vapor Deposition (PVD) can serve as one of the alternatives to minimize this issue. Past reports highlighted that coated PVD layer consists of pores, pin holes and columnar growth which act as channels for the aggressive medium to attack the substrate. Duplex and multilayer coatings seem able to address this issue at certain extent but at the expense of manufacturing time and cost. In the present work, the effect of ultrasonic vibration parameters on PVD-Titanium Nitride (TiN) coated Ti-13Zr-13Nb biomedical alloy was studied. Disk type samples were prepared and coated with TiN at various conditions: bias voltage (-125V), substrate temperature (100 to 300 ºC) and nitrogen gas flow rate (100 to 300 sccm). Ultrasonic vibration was then subsequently applied on extreme high and low conditions of TiN coated samples at two different frequencies (8 kHz, 16 kHz) and three set of exposure times (5 min, 8 min, 11 min). Encouraging results of PVD coating are observed on the samples coated at higher polarity of nitrogen gas flow rate (300 sccm) and substrate temperature (300 ºC) in terms of providing better surface morphology and roughness, coating thickness and adhesion strength. All TiN coated samples treated with ultrasonic vibration exhibit higher corrosion resistance than the untreated ones. Microstructure analysis under (Field Emission Scanning Electron Microscopy (FESEM) confirms that the higher ultrasonic frequency (16 kHz) and the longer exposure time (11 minutes) produce the most compact coating. It is believed that hammering effect from ultrasonic vibration reduces the micro channels’ size in the coating and thus decelerates the corrosion attack. Nano indentation test conducted on the ultrasonic treated samples provides a higher Hardness/Elasticity (H/E) ratio than untreated ones. This suggests that the ultrasonic vibration treated samples could also have a lower wear rate.
format Thesis
qualification_name Doctor of Philosophy (PhD.)
qualification_level Doctorate
author Abdullah, Arman Shah
author_facet Abdullah, Arman Shah
author_sort Abdullah, Arman Shah
title Influence of ultrasonic vibration on TiN coated biomedical TI-13Zr-13Nb alloy
title_short Influence of ultrasonic vibration on TiN coated biomedical TI-13Zr-13Nb alloy
title_full Influence of ultrasonic vibration on TiN coated biomedical TI-13Zr-13Nb alloy
title_fullStr Influence of ultrasonic vibration on TiN coated biomedical TI-13Zr-13Nb alloy
title_full_unstemmed Influence of ultrasonic vibration on TiN coated biomedical TI-13Zr-13Nb alloy
title_sort influence of ultrasonic vibration on tin coated biomedical ti-13zr-13nb alloy
granting_institution Universiti Teknologi Malaysia, Faculty of Mechanical Engineering
granting_department Faculty of Mechanical Engineering
publishDate 2015
url http://eprints.utm.my/id/eprint/54826/1/ArmanShahAbdullahPFKM2015.pdf
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