Pencirian morfologi, optik dan struktur untuk filem nipis hibrid polimer P3HT/partikel-partikel nano CdS dan CdSe
<p>Kajian ini bertujuan untuk melakukan pencirian morfologi, optik dan struktur bagi</p><p>mengkaji kehadiran partikel-partikel nano CdS dan CdSe yang tertanam di antara</p><p>matriks P3HT peranti filem nipis hibrid organik dan ta...
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QC Physics Azyuni Aziz Pencirian morfologi, optik dan struktur untuk filem nipis hibrid polimer P3HT/partikel-partikel nano CdS dan CdSe |
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<p>Kajian ini bertujuan untuk melakukan pencirian morfologi, optik dan struktur bagi</p><p>mengkaji kehadiran partikel-partikel nano CdS dan CdSe yang tertanam di antara</p><p>matriks P3HT peranti filem nipis hibrid organik dan tak organik menggunakan teknik</p><p>Pemendapan Angkutan Sudut (ALD) dan kaedah dedahan gas yang mudah, cepat dan</p><p>berkos rendah. Penyelidikan bermula dengan menentukan kesan kehadiran ion Cd2+</p><p>dalam larutan P3HT, asid stearik (SA) dan P3HT:SA yang dicirikan dengan isoterma</p><p>tekanan permukaan-luas yang dikawal oleh komputer. Peranti filem nipis disediakan</p><p>dengan memendapkan P3HT, SA dan ion Cd2+ (dalam kemolaran 0.5 dan 1.0 mM</p><p>CdCl2) ke atas substrat silikon dan kuarza menggunakan teknik ALD dan dedahan</p><p>kepada gas H2S atau H2Se selama 2, 4, 6 dan 15 jam. Peranti filem nipis organik-tak</p><p>organik dicirikan menggunakan FESEM, EDX, AFM, spektroskopi Raman dan UVVis.</p><p>Pencirian isoterma tekanan permukaan-luas menunjukkan purata keluasan dan</p><p>saiz molekul P3HT, SA dan P3HT:SA meningkat dengan peningkatan ion Cd2+.</p><p>Pembentukan partikel-partikel nano berjaya ditanam di antara matriks P3HT dengan</p><p>menggunakan kedua-dua kaedah seperti yang disahkan oleh keputusan FESEM, EDX</p><p>dan AFM. Pencirian Raman menunjukkan anjakan puncak ke nombor gelombang</p><p>lebih rendah apabila tempoh dedahan meningkat, menunjukkan peningkatan dalam</p><p>kristalografi polimer P3HT dan perlanjutan panjang konjugasi yang berkesan di</p><p>sepanjang tulang belakang polimer. Pencirian optik UV-Vis menunjukkan nilai tenaga</p><p>lebar jalur adalah antara 1.87 sehingga 1.91 eV. Sebagai kesimpulan, hasil pencirian</p><p>morfologi, optik dan struktur menunjukkan kehadiran partikel-partikel nano CdS atau</p><p>CdSe yang tertanam di antara matriks P3HT menggunakan kaedah ALD dan dedahan</p><p>gas. Polimer hibrid terbaik ialah P3HT:CdS dalam kemolaran 0.5 mM CdCl2 yang</p><p>didedahkan selama 6 jam. Kajian ini memberi implikasi bahawa teknik pemendapan</p><p>ALD dan dedahan gas adalah praktikal untuk menghasilkan peranti hibrid</p><p>nanokomposit organik-tak organik berkos rendah.</p> |
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Azyuni Aziz |
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Azyuni Aziz |
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Azyuni Aziz |
| title |
Pencirian morfologi, optik dan struktur untuk filem nipis hibrid polimer P3HT/partikel-partikel nano CdS dan CdSe |
| title_short |
Pencirian morfologi, optik dan struktur untuk filem nipis hibrid polimer P3HT/partikel-partikel nano CdS dan CdSe |
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Pencirian morfologi, optik dan struktur untuk filem nipis hibrid polimer P3HT/partikel-partikel nano CdS dan CdSe |
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Pencirian morfologi, optik dan struktur untuk filem nipis hibrid polimer P3HT/partikel-partikel nano CdS dan CdSe |
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Pencirian morfologi, optik dan struktur untuk filem nipis hibrid polimer P3HT/partikel-partikel nano CdS dan CdSe |
| title_sort |
pencirian morfologi, optik dan struktur untuk filem nipis hibrid polimer p3ht/partikel-partikel nano cds dan cdse |
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Universiti Pendidikan Sultan Idris |
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Fakulti Sains dan Matematik |
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2021 |
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oai:ir.upsi.edu.my:75992022-10-28 Pencirian morfologi, optik dan struktur untuk filem nipis hibrid polimer P3HT/partikel-partikel nano CdS dan CdSe 2021 Azyuni Aziz QC Physics <p>Kajian ini bertujuan untuk melakukan pencirian morfologi, optik dan struktur bagi</p><p>mengkaji kehadiran partikel-partikel nano CdS dan CdSe yang tertanam di antara</p><p>matriks P3HT peranti filem nipis hibrid organik dan tak organik menggunakan teknik</p><p>Pemendapan Angkutan Sudut (ALD) dan kaedah dedahan gas yang mudah, cepat dan</p><p>berkos rendah. Penyelidikan bermula dengan menentukan kesan kehadiran ion Cd2+</p><p>dalam larutan P3HT, asid stearik (SA) dan P3HT:SA yang dicirikan dengan isoterma</p><p>tekanan permukaan-luas yang dikawal oleh komputer. Peranti filem nipis disediakan</p><p>dengan memendapkan P3HT, SA dan ion Cd2+ (dalam kemolaran 0.5 dan 1.0 mM</p><p>CdCl2) ke atas substrat silikon dan kuarza menggunakan teknik ALD dan dedahan</p><p>kepada gas H2S atau H2Se selama 2, 4, 6 dan 15 jam. Peranti filem nipis organik-tak</p><p>organik dicirikan menggunakan FESEM, EDX, AFM, spektroskopi Raman dan UVVis.</p><p>Pencirian isoterma tekanan permukaan-luas menunjukkan purata keluasan dan</p><p>saiz molekul P3HT, SA dan P3HT:SA meningkat dengan peningkatan ion Cd2+.</p><p>Pembentukan partikel-partikel nano berjaya ditanam di antara matriks P3HT dengan</p><p>menggunakan kedua-dua kaedah seperti yang disahkan oleh keputusan FESEM, EDX</p><p>dan AFM. Pencirian Raman menunjukkan anjakan puncak ke nombor gelombang</p><p>lebih rendah apabila tempoh dedahan meningkat, menunjukkan peningkatan dalam</p><p>kristalografi polimer P3HT dan perlanjutan panjang konjugasi yang berkesan di</p><p>sepanjang tulang belakang polimer. Pencirian optik UV-Vis menunjukkan nilai tenaga</p><p>lebar jalur adalah antara 1.87 sehingga 1.91 eV. Sebagai kesimpulan, hasil pencirian</p><p>morfologi, optik dan struktur menunjukkan kehadiran partikel-partikel nano CdS atau</p><p>CdSe yang tertanam di antara matriks P3HT menggunakan kaedah ALD dan dedahan</p><p>gas. Polimer hibrid terbaik ialah P3HT:CdS dalam kemolaran 0.5 mM CdCl2 yang</p><p>didedahkan selama 6 jam. Kajian ini memberi implikasi bahawa teknik pemendapan</p><p>ALD dan dedahan gas adalah praktikal untuk menghasilkan peranti hibrid</p><p>nanokomposit organik-tak organik berkos rendah.</p> 2021 thesis https://ir.upsi.edu.my/detailsg.php?det=7599 https://ir.upsi.edu.my/detailsg.php?det=7599 text zsm closedAccess Masters Universiti Pendidikan Sultan Idris Fakulti Sains dan Matematik <p>Aberle A. G. (2009). Thin-film solar cells, Thin Solid Films 517, 47064710.</p><p>Doi:10.1016/j.tsf.2009.03.056.</p><p></p><p>Acharya, K. P. (2009). Photocurrent Spectroscopy of CdS/Plastic, CdS/Glass, and ZnTe/GaAs</p><p>Heteropairs Formed with Pulsed-Laser Deposition. 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