The effect of growth temperatures and substrate orientations of indium gallium phosphide quantum wires

Indium gallium phosphide (InGaP) nanowires were grown on gallium arsenide (GaAs) substrate by using metal-organic chemical vapour deposition (MOCVD) via vapour-liquid-solid (VLS) technique. The grown InGaP wires were characterized by using scanning electron microscopy (SEM), field emission scanning...

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Main Author: Nor Helmi, Nor Hamizah
Format: Thesis
Language:English
Published: 2014
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Online Access:http://eprints.utm.my/id/eprint/53451/25/NorHamizahNorHelmiMFS2014.pdf
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spelling my-utm-ep.534512020-07-15T02:30:20Z The effect of growth temperatures and substrate orientations of indium gallium phosphide quantum wires 2014-12 Nor Helmi, Nor Hamizah QC Physics Indium gallium phosphide (InGaP) nanowires were grown on gallium arsenide (GaAs) substrate by using metal-organic chemical vapour deposition (MOCVD) via vapour-liquid-solid (VLS) technique. The grown InGaP wires were characterized by using scanning electron microscopy (SEM), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX). The results showed that the growth of the InGaP wires depend strongly on the growth temperatures and substrate orientations. At low temperature of 380°C, wires grown on GaAs substrates were almost cylinderlike, while with increasing temperatures ranging from 410-500°C, the reversetapering phenomenon occurred producing microphone-like InGaP nanowires. With increasing temperature from 380-500°C, Au alloy-seed particle or the head part of the InGaP nanowires were also observed to be thicker in diameter (85-452 nm) than the body part (49.2-224.3 nm), which had been proven by the chemical compositions percentage in EDX analysis. Wires grown on GaAs (100) substrate were less than number of wires on GaAs (111) B substrate although wires on both substrates are basically grown on random directions. Twin boundaries crystal defects have been detected on some of the InGaP nanowires structures from TEM analysis. Such defects are not good and should be avoided to prevent further problem when being incorporated into potential devices. The crystal structure for all samples of InGaP wires is zinc blende (ZB), the lattice spacing (d) of InGaP wires is 3.342A, and the lattice parameter (a) is 5.788A. 2014-12 Thesis http://eprints.utm.my/id/eprint/53451/ http://eprints.utm.my/id/eprint/53451/25/NorHamizahNorHelmiMFS2014.pdf application/pdf en public http://dms.library.utm.my:8080/vital/access/manager/Repository/vital:85311 masters Universiti Teknologi Malaysia, Faculty of Science Faculty of Science
institution Universiti Teknologi Malaysia
collection UTM Institutional Repository
language English
topic QC Physics
spellingShingle QC Physics
Nor Helmi, Nor Hamizah
The effect of growth temperatures and substrate orientations of indium gallium phosphide quantum wires
description Indium gallium phosphide (InGaP) nanowires were grown on gallium arsenide (GaAs) substrate by using metal-organic chemical vapour deposition (MOCVD) via vapour-liquid-solid (VLS) technique. The grown InGaP wires were characterized by using scanning electron microscopy (SEM), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDX). The results showed that the growth of the InGaP wires depend strongly on the growth temperatures and substrate orientations. At low temperature of 380°C, wires grown on GaAs substrates were almost cylinderlike, while with increasing temperatures ranging from 410-500°C, the reversetapering phenomenon occurred producing microphone-like InGaP nanowires. With increasing temperature from 380-500°C, Au alloy-seed particle or the head part of the InGaP nanowires were also observed to be thicker in diameter (85-452 nm) than the body part (49.2-224.3 nm), which had been proven by the chemical compositions percentage in EDX analysis. Wires grown on GaAs (100) substrate were less than number of wires on GaAs (111) B substrate although wires on both substrates are basically grown on random directions. Twin boundaries crystal defects have been detected on some of the InGaP nanowires structures from TEM analysis. Such defects are not good and should be avoided to prevent further problem when being incorporated into potential devices. The crystal structure for all samples of InGaP wires is zinc blende (ZB), the lattice spacing (d) of InGaP wires is 3.342A, and the lattice parameter (a) is 5.788A.
format Thesis
qualification_level Master's degree
author Nor Helmi, Nor Hamizah
author_facet Nor Helmi, Nor Hamizah
author_sort Nor Helmi, Nor Hamizah
title The effect of growth temperatures and substrate orientations of indium gallium phosphide quantum wires
title_short The effect of growth temperatures and substrate orientations of indium gallium phosphide quantum wires
title_full The effect of growth temperatures and substrate orientations of indium gallium phosphide quantum wires
title_fullStr The effect of growth temperatures and substrate orientations of indium gallium phosphide quantum wires
title_full_unstemmed The effect of growth temperatures and substrate orientations of indium gallium phosphide quantum wires
title_sort effect of growth temperatures and substrate orientations of indium gallium phosphide quantum wires
granting_institution Universiti Teknologi Malaysia, Faculty of Science
granting_department Faculty of Science
publishDate 2014
url http://eprints.utm.my/id/eprint/53451/25/NorHamizahNorHelmiMFS2014.pdf
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